Semiconductor device manufacturing: process – Chemical etching – Liquid phase etching
Reexamination Certificate
2002-07-15
2004-04-20
Ho, Hoai (Department: 2818)
Semiconductor device manufacturing: process
Chemical etching
Liquid phase etching
Reexamination Certificate
active
06723658
ABSTRACT:
BACKGROUND OF THE INVENTION
The invention relates to electronic semiconductor devices, and, more particularly, to gate structures and fabrication methods for integrated circuits.
The trend in semiconductor integrated circuits to higher device densities by down-scaling structure sizes and operating voltages has led to silicon field effect (MOS) transistor gate dielectrics, typically made of silicon dioxide, to approach thicknesses on the order of 1-2 nm to maintain the capacitive coupling of the gate to the channel. However, such thin oxides present leakage current problems due to carrier tunneling through the oxide. Consequently, alternative gate dielectrics with greater dielectric constants to permit greater physical thicknesses have been proposed. Indeed, Ta
2
O
5
, (Ba,Sr)TiO
3
, and other high dielectric constant materials have been suggested, but such materials have poor interface stability with silicon.
Wilk and Wallace, Electrical Properties of Hafnium Silicate Gate Dielectrics Deposited Directly on Silicon, 74 Appl. Phys. Lett. 2854 (1999), disclose measurements on capacitors with a hafnium silicate dielectric formed by sputtering deposition (at a pressure of 5×10
−6
mTorr and substrate temperature of 500° C.) of a 5 nm thick Hf
6
Si
29
O
65
(Hf
0.18
Si
0.89
O
2
) layer directly onto silicon together with a gold top electrode deposition onto the silicate dielectric. Such capacitors showed low leakage current, thermal stability, an effective dielectric constant of about 11, and a breakdown field of 10 MV/cm.
However, such high-k dielectrics have problems with high volume production of silicon integrated circuits such as effective etches.
SUMMARY OF THE INVENTION
The present invention provides integrated circuit fabrication with metal silicate gate dielectrics by use of silicates etches including nitric acid with added peroxide and fluoride.
REFERENCES:
patent: 6284721 (2001-09-01), Lee
patent: 6455330 (2002-09-01), Yao et al.
patent: 6514808 (2003-02-01), Samavedam et al.
patent: 6551943 (2003-04-01), Eissa et al.
patent: 6555879 (2003-04-01), Krivokapic et al.
patent: 6624086 (2003-09-01), Eissa
Eissa Mona M.
Rotondaro Antonio L. P.
Brady W. James
Ho Hoai
Hoang Quoc
Hoel Carlton H.
Telecky , Jr. Frederick J.
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