Gas plasma polymerized permselective membrane

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210490, 427489, 427491, 427495, 4283139, 4283142, 4283157, 4283159, 4283199, 428447, 428451, B32B 2732, B01D 5322

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active

054397367

ABSTRACT:
Plasma polymerization of a fully alkylated disiloxane is greatly enhanced by the addition of oxygen to the plasma feed gases. Deposition rate of polysiloxane polymerizate upon substrates is increased, and the deposits are nontacky. Composite permselective membranes made by deposition of plasma-polymerized polysiloxanes in the presence of oxygen are useful for applications such as gas separations. Composite hollow fiber membranes of polysiloxane polymerizate on porous polypropylene exhibit oxygen
itrogen permselectivities greater than 2.3 combined with increased oxygen permeability.

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patent: 4824444 (1989-04-01), Nomura
Yamamoto et al., Plasma Polymerized Membranes and Gas Permeability I., J. Appl. Polymer Sci., 29, pp. 2981-2987 (1984).
Sakata et al., Plasma Polymerized Membranes and Gas Permeability II., J. Applied Polymer Sci., 31, pp. 1999-2006 (1986).
Kramer et al., Low Temperature Plasma for the Preparation of Separation Membranes, J. Membrane Science, 46, pp. 1-28 (1989).
Inagaki et al. "Preparation of Siloxane-Like Films by Glow Discharge Polymerization", J. Appl. Polyer Sci., 29 (1984) pp. 3595-3605.
Inagaki et al., "Plasma Polymerization Organosilicon Compounds", J. Appl. Polymer Sci., 30 (1985) 3385-3395.

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