Fungicides for the control of take-all disease of plants

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Having -c- – wherein x is chalcogen – bonded directly to...

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514332, 514336, 514344, 514345, 514348, 514349, 514350, 514351, 514352, 514354, 514355, 514357, 546 14, 546255, 546268, 546275, 546290, 546296, 546300, 546304, 546307, 546310, 546313, 546314, 546315, 546328, 546329, 546331, C07D21360, C07D21374, A01N 4340

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active

057055130

ABSTRACT:
A compound, composition, and method for controlling Take-all disease of plants by applying to the seed prior to planting, a fungicide of the formula: ##STR1## wherein Z.sub.1 and Z.sub.2 are C and are part of an aromatic ring which is pyridine; R and n are defined herein; A is selected from the group consisting of --C(O)--SR.sub.3, --NH--C(X)R.sub.4, --C(.dbd.NR.sub.3)--XR.sub.7, and --C(X)-amine wherein the amine is substituted with with an alkylaminocarbonyl and a hydrogen or wherein the amine has a first and a second amine substituent defined herein; B is --W.sub.m --Q(R.sub.2).sub.3 or selected from 0-tolyl, 1-naphthyl, 2-naphthyl, and 9-phenanthryl, each optionally substituted with halogen or R.sub.4 ; Q is C, Si, Ge, or Sn; W is --C(R.sub.3).sub.p H.sub.(2-p) --; or when Q is C, W may also be selected from --N(R.sub.3).sub.m H(.sub.1-m)--, --S(O)p--, and --O--; X is O or S; n is 0, 1, 2, or 3; m is 0 or 1; p is 0, 1, or 2; each R.sub.2 is independently selected from alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl and phenyl, each optionally substituted with R.sub.4 or halogen; and wherein, when Q is C, R.sub.2 may also be selected from halo, alkoxy, alkylthio, alkylamino, and dialkylamino; or wherein two R.sub.2 groups may be combined to form a cyclo group with Q which is 1-methylcyclopropyl, 1-methylcyclobutyl, 1-methylcyclopentyl, or 1-methylcyclohexyl; R.sub.3 is C.sub.1 -C.sub.4 alkyl; R.sub.4 is C.sub.1 -C.sub.4 alkyl, haloalkyl, alkoxy, alkylthio, alkylamino, or dialkylamino; and R.sub.7 is C.sub.1 -C.sub.4 alkyl, haloalkyl, or phenyl, optionally substituted with halo, nitro, or R.sub.4 ; or an agronomic salt thereof.

REFERENCES:
patent: 4228165 (1980-10-01), Ogata et al.
patent: 4248869 (1981-02-01), Ogata et al.
patent: 4485105 (1984-11-01), Ghepord et al.
patent: 4997836 (1991-03-01), Sugihara et al.
patent: 4999381 (1991-03-01), Crowley et al.
Carpenter, et al., "The Scope and Limitations of Carboxamide-Induced .beta.-Directed Metalation of 2-Substituted Furan, Thiophene, and 1-Methylpyrrole Derivatives: Application of the Method to Syntheses of 2,3-Disubstituted Thiophenes and Furans," J. Org. Chem. (1985), vol. 50, pp. 4362-4368.
Chemical Abstract of JP 58 88,390 (May 26, 1983), CA 99:176047d (1983).
Meyers, et al., "Oxazolines as Activating Groups in Aromatic Substitution: Nucleophilic Displacement of o-Fluoro Substituents by Organometallics and Lithio Amides," Tetrahedron Letters (1978), No. 3, pp. 223-226.
Mills, et al., "Directed Ortho Metalation of N,N-Diethylbenzamides: Silicon Protection of Ortho Sites and the o-Methyl Group," J. Org. Chem. (1989), vol. 54, pp. 4372-4385.
Snieckus, Victor, "Directed Ortho Metalation: Tertiary Amide and o-Carbamate Directors in Synthetic Strategies for Polysubstituted Aromatics," Chemical Reviews (1990), vol. 90, pp. 879-933.
Eiglsperger, A., et al. "The Enantiomers of N,N-Dimethylthiobenzamides: Chromatographic Behavior and Rotational Barriers." J. of Molecular Structure, 126: 421-432, 1985.
Fitt, J.J., et al. "Ortho Lithiation of Thiobenzamides." J. of Organic Chemistry, 41(25): 4029-4031, 1976.
Fu, J.M., et al. "The Directed Ortho Metalation Connection to Aryl-Aryl Cross Coupling. A General Regiospecific Synthesis of Phenanthrols." Tetrahedron Letters, 29(43): 5459-5462, 1988.
Grimshaw, J., et al. "Electrochemical Reactions. Intermolecular Radical Substitution During the Reduction of 2-Halo-N-methylbenzamides." J. of Chem. Soc., Perkin Trans. 1, No. 22, pp. 2448-2455, 1977.
Ishibashi, H., et al. "Friedel-Crafts alkylation of phenyl silanes with Abs.: 112(1)7560x!.
McDonald, J.E., et al. "An Anomalous Metalation of a Trimethylsilyl Group" Tetrahedron Letters, 28(17): 1851-1852, 1987.
Mills, R.J., et al. "Directed Ortho Metalation of N,N-Diethylbenzamides. Silicon Protection of Ortho Sites and the o-Methyl Group." J. of Organic Chemistry, 54: 4372-4385, 1989.
Mills, R.J., et al. "Dilithiated Synthons of Tertiary Benzamides, Phthalamides, and O,O'-Aryl Dicarbamates." Tetrahedron Letters, 26(9): 1145-1148, 1985.
Ogata, Y., et al. "Photochemical ethoxycarbonylmethylation of alkylbenzenes with ethyl chloroacetate. MO calculation for prediction of orientation." 90(15):120661w!.
Reuvers, A.J.M., et al. "Chemistry of Neopentyl Derivatives--II. Restricted Rotation in 2,6-Disubstituted Neopentylbenzenes." Tetrahedron, 27: 3713-3721, 1971.
Salituro, F.G., et al. "Facile Synthesis of L-Kynurenine." J. of Organic Chemistry, 53(26): 6138-6139, 1988.
Slocum, D.W., et al. "Directed Metallation of Model Adrenaline Compounds." J.C.S. Chem. Comm., pp. 268-269, 1974.
Snieckus, Victor. "Directed Ortho Metalation. Tertiary Amide and O-Carbamate Directors in Synthetic Strategies for Polysubstituted Aromatics." Chemical Reviews, vol. 90, No. 6, 1990.
Takahasi, Y., et al. "Application of the ORMUCS Method to Structure-Activity Studies on the Fungicidal Activity of Mepronil Derivatives." Quant. Struct.-Act. Relat. 6(1): 17-21, 1987.
Ukita, M., et al. "Thermal dissociation of ethyl N-arylcarbamates in a vapor phase." Osaka Kogyo Gijutsu Shikensho Kiho, 36(2):53-58, 1985.
Pepin, et al. Chemical Abstract: 113-78409m. 1990.
Lacova, et al. Chemical Abstract: 110:231500u. 1989.
Fischer, et al. Chemical Abstract: 106:18386x. 1987.
Pavanetto, et al. Chemical Abstract: 103:101888w. 1985.
Montanari, et al. Chemical Abstract: 102:19477g. 1985.
Metzner, et al. Chemical Abstract: 91:187234y. 1979.
Ogata, et al. Chemical Abstract: 91:74332k. 1979.
Chemical Abstracts CA99:176047D, 1983.

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