Ferrocenium/alpha-cleavage photoinitiator systems for free radic

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Radiation sensitive composition or product or process of making

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430914, 430916, 430923, 430925, 430325, 430284, 522 22, 522 25, 522 12, 522 28, 522 29, 522 66, G03C 168, G03C 164

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active

047074329

ABSTRACT:
A free radical polymerizable composition comprising a free radical polymerizable material and a photoinitiator system therefor comprising appropriate amounts of an alpha-cleavage or homolytic bond cleavage, photoinitiator and a ferrocenium salt, said composition being suitable for use in the preparation of protective layers and photographic images.

REFERENCES:
patent: 4245029 (1981-01-01), Crivello
patent: 4525553 (1985-06-01), Rooney et al.
patent: 4537854 (1985-08-01), Crivello
Herman Sikaufman and Joseph J. Falcetta, eds., Introduction to Polymer Science and Technology: An SPE Textbook, John Wiley & Sons, Inc, New York, N.Y., 1977, pp. 56-62.
Green et al, "Photocross-Linkable Resin Systems", Journal of Macromolecular Science; Reviews of Macromolecular Chemistry, C21(2), pp. 187-273, 1981-82.

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