Semiconductor device manufacturing: process – Coating of substrate containing semiconductor region or of... – Insulative material deposited upon semiconductive substrate
Reexamination Certificate
1999-08-17
2001-01-23
Nelms, David (Department: 2818)
Semiconductor device manufacturing: process
Coating of substrate containing semiconductor region or of...
Insulative material deposited upon semiconductive substrate
C438S787000, C438S788000, C257S315000, C257S295000
Reexamination Certificate
active
06177362
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of Invention
The present invention relates to a method for fabricating an integrated circuit (IC). More particularly, the present invention relates to a fabrication method for a gate structure having gate dielectric layers of different thicknesses.
2. Description of Related Art
Commonly on the same chip, it is necessary to equip some circuits with a low voltage (LV) device and a high voltage (HV) device. For example, an erasable programmable read only memory (EPROM) has a HV transistor for programming and a LV logic device which requires the HV transistor to process a higher external power supply voltage. Since these two devices operate with different voltages, gate dielectric layers of different thicknesses are made to accommodate their different voltage needs. In particular, the HV transistor needs a thicker gate dielectric layer for accepting a higher voltage, while the LV transistor has a thinner gate dielectric layer. Besides EPROM, ULSI development in the future may produce several different voltages to be applied to the same chip. Thus, according to the oxide reliability, gate dielectric layers having different thicknesses are needed in response to different voltages.
FIGS. 1A
to
1
D are schematic, cross-sectional diagrams illustrating a conventional method for fabricating a gate structure having gate dielectric layers having different thicknesses.
Referring to
FIG. 1A
, an oxide layer
108
is formed on a substrate
100
of a flash memory region
102
, a HV region
104
, and a LV region
106
. A polysilicon layer (not shown) is formed on the oxide layer
108
and defined so that a floating gate
110
of the flash memory is formed only on the substrate
100
of the flash memory region
102
. An oxide-nitride oxide (ONO) layer (not shown) is formed on the substrate
100
, followed by forming a patterned photoresist (not shown) on the ONO layer. The ONO layer is defined to form an ONO dielectric layer
112
which covers the floating gate
110
on the substrate
100
of the flash memory region
102
. The oxide layer
108
on the substrate of the HV region
104
and the LV region
106
is then removed, while the patterned photoresist is also removed.
Referring to
FIG. 1B
, an oxidation process is performed, so that an oxide layer
114
is formed on the substrate
100
of the HV region
104
and the LV region
106
.
Referring to
FIG. 1C
, a patterned photoresist (not shown) is formed to cover the oxide layer
114
in the HV region
106
and the ONO dielectric layer
112
in the flash memory region
102
, while the oxide layer
114
in the LV region
106
is left exposed. With the patterned photoresist serving as an etching mask, the oxide layer
114
in the LV region
106
is removed until the surface of the substrate
100
in the LV region
106
is exposed. The patterned photoresist is removed to expose the oxide layer
114
in the HV region
104
. An oxidation process is further performed to form an oxide layer
118
on the oxide layer
114
in the HV region
104
and the substrate
100
in the LV region
106
. To simplify the description, the oxide layers
114
and
118
in the HV region are generally known as an oxide layer
116
.
Referring to
FIG. 1D
, a polysilicon layer (not shown) is formed on the substrate
100
. The polysilicon layer, the oxide layer
116
in the HV region
104
, and the oxide layer
118
in the LV region
106
are patterned so as to form a control gate
120
a
on the ONO dielectric layer
112
of the flash memory region
102
. Meanwhile, a HV gate structure
122
a
having a gate electrode
120
b
and a gate oxide layer
116
a
is formed in the HV region
104
, and a LV gate structure
122
b
having a gate electrode
120
c
and a gate oxide layer
118
b
is formed in the LV region
106
.
Conventionally, during the formation of the gate dielectric layers having different thicknesses, steps for forming and removing the patterned photoresist have to be repeated several times on the ONO dielectric layer and the oxide layers
108
,
114
, in order to obtain gate dielectric layers having different thicknesses. However, as these steps are repeated several times before formation of the control gate
120
a,
the gate electrodes
120
b,
120
c,
the ONO dielectric layer
112
and the oxide layers
108
,
114
are contaminated by the patterned photoresists. This has made it difficult to control the quality of the ONO dielectric layer
112
and the oxide layers
108
,
114
. The gate oxide layer
116
a,
in particular suffers from poor quality after several episodes of contamination by patterned photoresist. Thus, the gate dielectric layer of the device is unable to withstand a breakdown produced by the set voltage, leading to a reduction in the reliability of the gate dielectric layer. Furthermore, the control gate
120
a
is damaged by etching and oxygen diffusion in the subsequent photolithographic etching and thermal oxidation.
SUMMARY OF THE INVENTION
The invention provides a method for fabricating a gate structure having gate dielectric layers of different thicknesses. The method includes providing a substrate with a flash memory region a high voltage (HV) region, and a low voltage (LV) region. A dielectric layer is then formed on the substrate. A floating gate is formed on the first dielectric layer in the flash memory region, followed by forming in sequence a second dielectric layer, a first conducting layer, and a first protective layer on the first dielectric layer and the floating gate. The first protective layer, the first conducting layer, the second dielectric layer, and the first dielectric layer are partially removed until a substrate surface in the HV region and LV region is exposed. A third dielectric layer is then formed on the substrate in the HV and LV regions. The second protective layer, the second conducting layer, and the third dielectric layer are partially removed until the substrate surface in the LV region and the first protective layer of the flash memory region are exposed. A fourth dielectric layer is formed on the substrate in the LV region, followed by forming in sequence a third conducting layer and a third protective layer. Consequently, the second and the third protective layers, the second and the third conducting layers, and the third and the fourth dielectric layers are defined to form a HV structure in the HV region and a LV structure in the LV region. The first, the second, and the third protective layers in this case include silicon nitride or silicon oxy-nitride.
As embodied and broadly described herein, the first, the second, and the third conducting layers as well as the first, the second, and the third protective layers are respectively formed after the formation of the second, the third, and the fourth dielectric layers. As the dielectric layer and the photoresist involved in the photolithographic etching are effectively isolated from each other, the contamination of the dielectric layer by the photoresist is greatly reduced. Also, the dielectric layer is formed by performing oxidation once, so the dielectric layer formed as such has different compositions from that of the dielectric layer formed by double oxidation. Thus, the quality and reliability of the dielectric layer are greatly improved.
It is to be understood that both the foregoing general description and the following detailed description are exemplary, and are intended to provide further explanation of the invention as claimed.
REFERENCES:
patent: 5861347 (1999-01-01), Maiti et al.
patent: 5888869 (1999-03-01), Cho et al.
Hong Shih-Fang
Huang Chih-Jen
Nelms David
Thomas Kayden Horstemeyer & Risley
United Microelectronics Corp.
Vu David
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