Ethylene-vinyl acetate copolymer of increased mechanical...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

Reexamination Certificate

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C264S328170, C524S789000, C524S790000, C524S791000, C524S445000, C525S191000, C525S236000, C525S239000, C525S222000, C525S227000, C525S228000, C525S186000

Reexamination Certificate

active

07947774

ABSTRACT:
Solution blending of masterbatch of cationically functionalized polyvinyl acetate copolymer/silicate nanocomposite where the silicate is substantially exfoliated, and ethylene-vinyl acetate copolymer (EVA), produces product of increased tensile strength and Young's Modulus compared to neat EVA and reduced flammability compared to neat EVA. The product can be injection molded or compression molded or extruded without loss of these advantages.

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M. Valera-Zaragoza, E. Ramirez-Varga, F.J. Medellin-Rodriguez, B.M Huerta-Martinez, “Thermal stability and flammability properties of heterophasic PP-Ep/EVA/organoclay nanocomposites.” Oct. 10, 2005, pp. 1319-1325.
Shi., Synthesis and characterization of poly(vinyl acetate) and ethylene-vinylacetate silicate nanocomposites.
Shi, Y., et al., “Surfactant-Free Method for the Synthesis of Poly(vinyl acetate) Masterbatch Nanocomposites as a Route to Ethylene Vinyl Acetate/Silicate Nanocomposites”, Chem. Mater. 19(7), pp. 1552-1564, 2007—Supporting Information.
Alexandre, M., et al., “Preparation and Properties of Layered Silicate Nanocomposites Based on Ethylene Vinyl Acetate Copolymers”, Macromol. Rapid Commun. 22, pp. 643-646, 2001.
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