Etching of tantalum silicide/doped polysilicon structures

Adhesive bonding and miscellaneous chemical manufacture – Delaminating processes adapted for specified product – Delaminating in preparation for post processing recycling step

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29571, 29580, 134 1, 156646, 156651, 156656, 156657, 1566591, 156662, 204192EC, 204192E, 252 791, 427 85, 427 86, 427 93, H01L 21306, B44C 122, C03C 1500, C23F 102

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044117345

ABSTRACT:
A method of forming and anisotropically etching a structure on a substrate, said structure being comprised of a layer of doped polycrystalline silicon having thereover a layer of tantalum silicide. The method comprises providing a layer of polycrystalline silicon on the substrate, doping the silicon to render it conductive, preparing the surface of the silicon for deposition of tantalum silicide by treatment with a carbon tetrafluoride/oxygen plasma, depositing tantalum silicide thereon tantalum rich, anisotropically plasma etching the two-layered structure with an etchant mixture of carbon tetrachloride, oxygen and nitrogen, annealing the tantalum silicide layer and, if desired, covering the resultant structure with a protective layer of oxide. In a preferred embodiment, the silicon layer is deposited in the amorphorus state and annealed to the polycrystalline state.

REFERENCES:
patent: 4141022 (1979-02-01), Sigg et al.
patent: 4285761 (1981-08-01), Fatula, Jr. et al.
patent: 4332839 (1982-06-01), Levinstein et al.
patent: 4362597 (1982-12-01), Fraser et al.
Pure and Applied Chemistry, vol. 52, pp. 1759-1765 (1980).

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