Adhesive bonding and miscellaneous chemical manufacture – Delaminating processes adapted for specified product – Delaminating in preparation for post processing recycling step
Patent
1989-07-17
1990-05-15
Powell, William A.
Adhesive bonding and miscellaneous chemical manufacture
Delaminating processes adapted for specified product
Delaminating in preparation for post processing recycling step
156651, 156654, 156668, 21912169, 21912176, B44C 122, B29C 3700
Patent
active
049255231
ABSTRACT:
A method and apparatus are described which enhance the ablative effect of a UV laser. The ablative effect of a pulsed UV laser is enhanced using a second, longer wavelength pulsed laser. Each pulse of the first laser is followed by or combined with a pulse from the second laser. The etch depth per pulse is controlled by varying the time between pulses from the first and second lasers. The maximum etch depth per pulse occurs at a time separation which is a function of the substrate being etched. The first laser wavelength is selected to be within the absorption spectrum of the unexcited surface molecules of the substrate, while the wavelength of the second laser is selected to be within the absorption spectrum of the surface molecules excited by the incident radiation of the first laser.
REFERENCES:
patent: 3622742 (1971-11-01), Cohen et al.
patent: 3710798 (1973-01-01), Bredemeier
patent: 4054094 (1977-10-01), Caddell et al.
patent: 4289378 (1981-09-01), Remy et al.
patent: 4408602 (1983-10-01), Nakijima
patent: 4414059 (1983-11-01), Blum et al.
patent: 4417948 (1983-11-01), Mayne-Banton et al.
patent: 4440801 (1984-04-01), Aviram et al.
patent: 4451503 (1984-05-01), Blum et al.
patent: 4508749 (1985-04-01), Brannon et al.
patent: 4568632 (1986-02-01), Blum et al.
patent: 4627436 (1986-12-01), Leckrone
patent: 4687539 (1987-08-01), Burns et al.
patent: 4701591 (1987-10-01), Masaki et al.
patent: 4715318 (1987-12-01), Kameyama et al.
patent: 4749840 (1988-06-01), Piwczyk
patent: 4784135 (1988-11-01), Blum et al.
D. L. Klein et al., "Ablative Photocomposition Process for Repair of Line Shorts," IBM Technical Disclosure Bulletin, vol. 26, No. 9 (2/84), p. 4669.
R. Srinivasan et al., "Mechanism of the Ultraviolet Laser Ablation of Polymethyl Methacrylate at 193 and 248 nm: Laser-Induced Fluorescence Analysis Chemical Analysis, and Doping Studies", J. Opt. Soc. Am.B/vol. 3, No. 5 (5/86), p. 785.
R. Srinivasan et al., "Ablative Photodecomposition of Polymer Films by Pulsed Far-Ultraviolet (193 nm) Laser Radiation: Dependence of Etch Depth on Experimental Conditions," J. Pol. Science, vol. 22, p. 2601 (1984).
B. J. Garrison et al., "Laser Ablation of Organic Polymers: Microscopic Models for Photochemical and Thermal Processes," J. Appl. Phys., 57 (8), p. 2909 (4/15/85).
J. T. C. Yeh, "Laser Ablation of Polymers," J. Vac. Sci. Technol. A 4 (3), p. 653 (May/Jun. 1986).
R. Srinivasan et al., "Photochemical Cleavage of a Polymeric Solid: Details of the Ultraviolet Laser Ablation of Poly(Methyl Methacrylate) at 193 and 248 nm," Macromolecules, vol. 19, p. 916 (1986).
B. Braren et al., "Optical and Photochemical Factors which Influence Etching of Polymers by Ablative Photodecomposition," J. Vac. Sci. Technol. B 3 (3), p. 913 (May/Jun. 1985).
G. Koren, "CO.sub.2 Laser Assisted UV Ablative Photoetching of Kapton Films," Appl. Phys. Lett., vol. 45, No. 1, Jul. 1984, pp. 10-12.
M. Stuke & R. Larciprete, "Direct Observation of Excimer Laser Photoablation Products by Picosecond-UV-Laser Mass Spectroscopy," Applied Physics, Mar. 1986, pp. 57-58.
R. Srinivasan and V. Mayne-Banton, "Self-Developing Photoetching of Poly (Ethylene Terephthalate) Films by Far-Ultraviolet Excimer Laser Radiation," Appl. Phys. Lett. 41 (6), pp. 576-578 (9/15/82).
R. Srinivasan and W. J. Leigh, "Ablative Photodecomposition: Action of Far-Ultraviolet (193 nm) Laser Radiation on Poly (Ethylene Terephthalate) Films," Journal of the American Chemical Society, 104, 6784 (1982).
G. Koren and J. T. C. Yeh, "Emission Spectra, Surface Quality, and Mechanism of Excimer Laser Etching of Polyimide Films," Appl. Phys. Lett., 44 (12), pp. 1112-1114 (6/15/84).
G. Koren and J. T. C. Yeh, "Emission Spectra and Etching of Polymers and Graphite Irradiated by Excimer Lasers," J. Appl. Phys., 56 (7), pp. 2120-2126 (10/1/84).
J. E. Andrew, P. E. Dyer, D. Forster and P. H. Key, "Direct Etching of Polymeric Materials Using a XeCl Laser," Appl. Phys. Lett., 43 (8), pp. 717-719 (10/15/83).
E. Sutcliffe and R. Srinivasan, "Dynamics of UV Laser Ablation of Organic Polymer Surfaces," J. Appl. Phys., 60 (9), pp. 3315-3322 (11/1/86).
R. Srinivasan, E. Sutcliffe and B. Braren, "Analysis of the Dynamics of the Interaction of Ultraviolet Lasers with Organic Polymers," Laser Chem., vol. 9, pp. 147-154 (1988).
Braren Bodil E.
Srinivasan Rangaswamy
International Business Machines - Corporation
Powell William A.
Shay Bernard E.
LandOfFree
Enhancement of ultraviolet laser ablation and etching organic so does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Enhancement of ultraviolet laser ablation and etching organic so, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Enhancement of ultraviolet laser ablation and etching organic so will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-619725