Encapsulated-metal vertical-interdigitated capacitor and...

Active solid-state devices (e.g. – transistors – solid-state diode – Field effect device – Having insulated electrode

Reexamination Certificate

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C257S306000, C257S309000

Reexamination Certificate

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06441419

ABSTRACT:

FIELD OF THE INVENTION
This invention relates to capacitors formed in integrated circuits (ICs). More particularly, the present invention relates to a new and improved encapsulated metal vertical interdigitated capacitor located between interconnect layers of an IC, and a damascene method of making the same. The capacitor construction allows highly conductive metal, such as copper, to be used as conductors in the interconnect layers and to contact the plates of the capacitor while deterring metal atom diffusion or metal ion migration which may occur under elevated temperature conditions or biasing conditions and to prohibit and to prevent adverse effects from such migration, among other things. The damascene method of manufacturing the capacitor avoids difficult-to-execute etching steps which would otherwise be required to fabricate the capacitor and the IC while simultaneously avoiding residual accumulations of material in openings following chemical mechanical polishing steps required to form the multiple interconnect layers, among other things.
BACKGROUND OF THE INVENTION
Modern integrated circuits (ICs) are frequently constructed using multiple layers or levels of electrical conductors formed above a substrate into which the functional devices of the IC are formed. Each level of electrical conductors is referred to as an “interconnect layer.” Multiple interconnect layers are advantageous in ICs because valuable substrate space is not excessively consumed by the electrical connections between the various components. Instead, the electrical conductors of each interconnect layer route the signals between many of the functional components in the substrate. The ability to construct ICs with multiple interconnect layers has come about as a result of planarization techniques such as chemical mechanical polishing (CMP).
In addition to routing the electrical signals by conductors outside the substrate, the interconnect layers have also been employed for additional beneficial functions, such as the incorporation of capacitors in interlayer dielectric (ILD) insulating material which separates the electrical conductors of the vertically separated interconnect layers, and the incorporation of capacitors with the conductors of the interconnect layers themselves. The above referenced U.S. patent applications all pertain to the incorporation of capacitors with the interconnect layers and to a technique for vertically orienting portions of the capacitor plates between the interconnect layers to maximize the amount of capacitance obtained relative to the horizontal surface area consumed.
The first two above referenced U.S. patent applications, “Vertically Interdigitated Metal-Insulator-Metal Capacitor for an Integrated Circuit” and “Process for Fabricating Vertical Interdigitated Metal-Insulator-Metal Structure within an Integrated Circuit” describe a capacitor structure and fabrication process which has the advantage of forming vertical plate capacitors between the interconnect layers using CMP process steps when openings in the structure are not present, thereby avoiding the accumulation of residual slurry material from the CMP process and resist material from the subsequent photolithographic process in the openings. Residual slurry material accumulated in the openings creates subsequent fabrication difficulties and defects in the resulting IC. For example, residual photoresist will outgas when metal is applied over it. The outgas effect prevents the metal from depositing properly, if at all. Inadequately deposited metal may result in open or unreliable circuit connections, thereby degrading the functionality of the IC or capacitor. Residual materials are extremely difficult to remove completely from the opening, and attempts to do so add additional process steps and may even raise the risk that the other existing circuit components will be damaged by the cleaning process itself.
The two applications mentioned in the preceding paragraph describe the inventions in the context of conventional aluminum electrical conductors in the interconnect layers and tungsten filling openings adjoining the upper capacitor plates and in via plug interconnects extending between the interconnect layers. Aluminum is typically used as a major component of the interconnect layer conductors because aluminum is relatively easily formed into desired conductor patterns by use of conventional photolithographic patterning and etching techniques. Etching aluminum can be effectively accomplished in a relatively low temperature environment. The low temperature environment does not introduce adverse influences on the other components of the IC. For example, relatively high temperatures may cause metal conductors to expand and deform, or the relatively high temperatures may cause metal grain growth which deforms the structure. Such adverse influences may destroy the components or reduce their functionality. Tungsten is used as the fill material for similar reasons and because of its compatibility with materials typically used in semiconductor processing.
Ideally, it would be more advantageous to use copper rather than aluminum for the conductors in the interconnect layer or tungsten as the fill material in the vias. Copper is more conductive than aluminum, thus allowing for less signal attenuation, smaller signal propagation delays and higher operating frequencies in the IC circuitry. However, plasma etching of copper in semiconductor fabrication requires a much higher temperature than the temperature required to plasma etch aluminum, thus causing the aforementioned temperature-induced adversities. At the present time there are no known cost-effective plasma etching techniques suitable for copper. Furthermore, atoms or ions of copper from copper conductors may diffuse or migrate throughout the insulating and other materials on the IC, including the substrate, and destroy the effectiveness of the functional devices and the insulators.
While it is known to encapsulate copper conductors in barrier metal to prevent or substantially inhibit the migration of the copper ions and the diffusion of copper atoms throughout the IC structure, such encapsulation techniques involve additional process steps and add complexity to the overall IC fabrication.
It is with regard to these and other considerations that the present invention has evolved.
SUMMARY OF THE INVENTION
One aspect of this invention relates to a relatively high capacity capacitor formed between interconnect layers which uses copper or other high conductivity metal conductors or metals capable of atom diffusion or ion migration in a manner in which capacitor plates serve as barrier metal to prevent the atom diffusion and migration of copper ions from high conductivity metal conductors throughout the IC. A related aspect of this invention relates to using barrier metal to at least partially encapsulate the high conductivity or copper conductors of the interconnect layers as well as a capacitor plate, thereby simplifying the IC construction by not requiring a full complement of separate steps to encapsulate the high conductivity or copper conductors. Another aspect of this invention relates to a capacitor construction and fabrication process in which the elements of the capacitor are formed by damascene processes and chemical metal polishing (CMP) processes, thereby avoiding the necessity to etch the copper or other high conductivity metal of the interconnect layer conductors and also avoiding the problems created from high temperature etching. A further aspect of this invention utilizes CMP and other planarization processes during the formation of the capacitor when openings are present, to continue to obtain the advantages of avoiding the accumulation of residual slurry materials in openings and of avoiding the necessity of additional cleaning steps during the IC fabrication process. Still a further aspect of this invention pertains to forming via plug interconnects between the conductors of the interconnect layers using the same high conductivity material of the interc

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