Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge
Patent
1994-04-12
1995-11-28
Niebling, John
Chemistry: electrical and wave energy
Processes and products
Electrostatic field or electrical discharge
204106, 204278, 204279, 204288, 204289, C25C 706
Patent
active
054704456
ABSTRACT:
In a tank confined electrolysis process, such as electrowinning or electrorefining, having circulated electroplating solution containing sulfuric acid, a multi-element cover system is applied below the electrode conductor connections and above the surface of the electrolyte bath. This cover is evacuated in the interstices below the cover and above the bath at a rate exceeding the stoichiometric ratio causing any leakage to occur into the volume overlying the bath thereby preventing acid aerosol from escape. The rate of evacuation is restricted so that humidity is maintain under the cover and over the surface of the bath to prevent the formation of crystals formed from aerosol droplets which become supersaturated. In a preferred embodiment, a circular weir in combination with gas discharge over the weir to a downcomer is disclosed. Entrainment of air over the weir and into the downcomer is disclosed to provide sufficient pumping for evacuation.
REFERENCES:
patent: 4668353 (1987-03-01), Smith
patent: 5149411 (1992-09-01), Castle
Invention Deisclosure, "Oxide Tankhouse Anodes", Magma Copper Company, Apr. 26, 1985.
Magma Copper Company Interoffice Correspondence, "Oxide Tankhouse Anodes" M. F. Vancas, Apr. 26, 1985 (unpublished).
Bates Robert K.
Cox Terrance J.
Imrie William P.
Murray James A.
Nees Michael R.
Bechtel Group Inc.
Mee Brendan
Niebling John
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