Electrochemical sensor for reactive gas mixtures

Chemistry: electrical and wave energy – Processes and products – Vacuum arc discharge coating

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204 1T, G01n 2746

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active

039817857

ABSTRACT:
An electrochemical device is designed to respond to a constituent such as oxygen in a reactive mixture which may include a fuel such as methane. The device includes an electrochemical cell employing an electrolye such as a stabilized zirconia associated with two electrodes and designed for operation at an elevated temperature such as 200.degree.C to 1000.degree.C. An electrode for such a cell is designed to have no catalytic action on the mixture.
The system may be arrnaged to assure a full reaction of the mixture before the cell responds to the desired constituent. Thus the mixture may also be subjected to the action of a catalyst before it reaches the electrode area. If the mixture is applied to another non-catalytic cell before it is subjected to the catalyst further information is obtained concerning the desired constitent. The amount of a constituent such as oxygen present before and after the mixture is catalyzed may be compared to provide an indication of the amount of another constituent of the mixture such as methane.

REFERENCES:
patent: 3216911 (1965-11-01), Kronenberg
patent: 3347767 (1967-10-01), Hickam
patent: 3400054 (1968-09-01), Ruka et al.
patent: 3481855 (1969-12-01), Kolodney et al.
patent: 3514377 (1970-05-01), Spacil et al.
patent: 3597345 (1971-08-01), Hickam et al.

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