Dual damascene process

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

Reexamination Certificate

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Details

C438S637000, C438S638000, C438S666000, C438S672000, C438S687000

Reexamination Certificate

active

06495448

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates in general to the manufacture of semiconductor integrated circuits. More particularly, it relates to a dual damascene process for preventing photoresist contamination.
2. Description of the Related Art
In the semiconductor industry, much effort is spent developing semiconductor devices with high operating speeds. Due to rapid progress in integrated circuit (IC) fabrication technologies, the integration of the IC devices has increased, and raising the resistance of metal wires and the parasitic capacitance effect therebetween. The metal wires thus carry a current flow at a low speed. In order to reduce resistance and parasitic capacitance, low resistance material, such as copper, is used for metal wires, and low dielectric constant (low-k) materials are used for the insulating layer between the metal wires.
Recently, a dual damascene process using low-k dielectrics and low resistance metals has been developed to form high-reliability, low cost interconnects in the IC devices.
FIGS. 1
a
though
1
d
illustrate a conventional method for forming a dual damascene structure. In
FIG. 1
a,
a semiconductor substrate
100
is provided. A sealing layer
102
, a low-k dielectric layer
104
, and a mask layer
106
with a plurality of trench openings
106
a
are sequentially formed on the substrate
100
.
In
FIG. 1
b
, a photoresist layer
108
has been coated on the mask layer
106
and filled into the openings
106
a
. Next, lithography is performed on the photoresist layer
108
, thereby forming a patterned photoresist layer
108
with a plurality of via openings
108
a
aligned with the trench openings
106
a
overlaying the mask layer
106
and part of the dielectric layer
104
. Hence, however, photoresist contamination occurs due to amino elements in the dielectric layer
104
. As a result, sidewalls of the patterned photoresist layer
108
have poor profile.
In
FIG. 1
c,
the dielectric layer
104
is anisotropically etched using the patterned photoresist layer
108
as a mask, and the via pattern is then transferred into the upper half of the dielectric layer
104
.
In
FIG. 1
d,
the photoresist layer
108
is removed. Thereafter, the dielectric layer
104
is etched using the mask layer
106
with trench openings
106
a
, and using the sealing layer
102
as an etching stop layer. As a result, trench patterns are transferred into the upper half of the dielectric layer
104
, and the via patterns in the upper half of the dielectric layer
104
are simultaneously transferred into the lower half of the dielectric layer
104
. These trenches
104
b
and vias
104
a
formed in the dielectric layer
104
create a plurality of dual damascene structures. Next, the sealing layer
102
below the vias
104
a
is removed. Due to photoresist contamination mentioned above, a poor via profile in dual damascene structure results, and low IC device reliability results.
SUMMARY OF THE INVENTION
Accordingly, an object of the invention is to provide a dual damascene process for forming an additional cap layer on the dielectric, thereby preventing potentially contaminating photoresist contact with the dielectric layer.
Another object of the invention is to provide a dual damascene process for forming a cap layer as an anti-reflective layer (ARL) to improve the dual damascene structure profile.
To achieve these and other advantages, the invention provides a method of fabricating a dual damascene structure. First, a substrate having a dielectric layer is provided. A cap layer is formed on the dielectric layer, and a mask layer with at least one trench pattern is then deposited overlaying the cap layer. Thereafter, a photoresist layer with at least one via pattern aligned with the trench pattern is formed overlaying the mask layer and part of the cap layer. Next, the via pattern is transferred into the cap layer and the upper half of the dielectric layer. The photoresist layer is then removed. Subsequently, the trench pattern is transferred into the cap layer and the upper half of the dielectric layer, and simultaneously the via pattern in the upper half of the dielectric layer is transferred into the lower half of the dielectric layer. Finally, the trench and the via in the dielectric layer are filled with a conductive layer. In the invention, the cap layer is undoped silicate glass (USG), SiC or SiF, and chemical vapor deposition (CVD) using SiH
4
or tetraethyl orthosilicate (TEOS) as a reaction gas.


REFERENCES:
patent: 5916823 (1999-06-01), Lou et al.
patent: 6153528 (2000-11-01), Lan
patent: 6197681 (2001-03-01), Liu et al.
patent: 6331479 (2001-12-01), Li et al.
patent: 6362301 (2001-12-01), Venkatesan et al.

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