Dual alkali scrubber liquor regeneration with production of gyps

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Sulfur or sulfur containing component

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Details

423166, 423512A, 423519, C01B 1700, C01B 1745, C01B 1762

Patent

active

045405565

ABSTRACT:
A process for the recovery of gypsum as a product of a dual alkali system for regeneration of a sodium base alkaline scrubber liquor in which the liquor reacts with ground limestone in two serially connected sludge blankets containing from 15%-40% solids in a liquor matrix and overlain by a relatively clear supernatant pool. Upon completion of regeneration the liquor is discharged from the second blanket to the scrubber cycle while a proportionate amount of the slurry is further treated to reduce its pH and/or increase its density and/or to displace regenerated scrubber from the matrix after which the slurry is transferred to a separate tank and there oxidized to gypsum then it is filtered. The filtrate is returned to the liquor regeneration cycle and the gypsum recovered as product.

REFERENCES:
patent: 3961021 (1976-06-01), Morita et al.
patent: 3965242 (1976-06-01), Morita et al.
patent: 4462969 (1984-07-01), Wilhelm

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