Drying device for producing small quantities of controlled...

Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs

Reexamination Certificate

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Reexamination Certificate

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07867937

ABSTRACT:
Catalysts for experimentation are produced having a controlled matrix pore structure. The manufacturing process utilizes tape casting in the drying procedure in which a catalyst slurry is cast on a substrate and dried at a temperature of between about 50° C. to 200° C. for a period of time of about 0.1 to 1.0 hour. The dried catalyst particles can be removed from the substrate by several techniques, including scraping, burning, and deforming the substrate material. The resulting catalytic particles can be produced in an amount of about ca. 3 g to 300 g from slurries with volumes between 5 cc to 500 cc, which are suitable for small scale FCC reactors and for high throughput experimentation.

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Wang, X., et al., “Fabrication of Micro-Reactors using Tape-Casting Methods”, Catalysis Letters (2001), 77(4), 173-177.
Kimball, G., “Direct vs. Indirect Drying: Optimizing the Process”, Chemical Engineering, 108/5 74-81 (May 2001).
Ge, Shifu et al., “Drying Mechanism of Thin Film Coated on Particle Surface”, Huagong Xuebao/Journal of Chemical Industry and Engineering (China) v56, n1, Jan. 2005.
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Ma, H., et al., “Nano-Corundum—Synthesis and Use as Filtration Membranes, Catalyst Carriers, Wear Resistant Coatings and Sensors”, Chemical Engineering and Technology, 24/10, 1005-1008 (Oct. 2001).
Maier, Wilhelm F., “Combinatorial Catalyst Libraries: Preparation, Characterization, and Catalysis”, Book of Abstracts, 219thACS National Meeting, San Francisco, CA, Mar. 26-30, 2000, MTLS-002 (Publisher: American Chemical Society, Washington, D.C.).
Wang, X., et al, “Fabrication of micro-reactors using tape-casting methods”, Catalysis Letters (2001), 77(4), 173-177 Coden.—Abstract attached.
Kimball, G. “Direct vs indirect drying: Optimizing the process” Chemical Engineering 108/5 74-81 (May 2001)—Abstract attached.
Ge, S., et al. “Drying mechanism of thin film coated on particle surface” Huagong Xuebac/Journal of Chemical Industry and Engineering (China) v 56 n 1 Jan. 2005, p. 30-34 CODEN:—abstract attached.
Lebedev, V.Ya, et al., “Combined Drying of a Granulated Material in a Fluidized Bed Apparatus” J. Appl Chem USSR v 60 n 7 pt 1 Jul. 1987, p. 1450-1454 CODEN—abstract attached.
Ma, H., et al., “Nano-corundum—Synthesis and use as filtration membranes, catalyst carriers, wear resistant coatings and sensors”, Chemical Engineering and Technology 24/10 1005-1008 (Oct. 2001)—Abstract attached.
Maier, W.F., Combinatorial catalyst libraries: Preparation, characterization, and catalysis, Book of Abstracts, 219thACS Nat'l Meeting, San Francisco, CA., Mar. 26-30, 2000—Abstract attached.

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