Double layer photoresist technique for side-wall profile control

Adhesive bonding and miscellaneous chemical manufacture – Delaminating processes adapted for specified product – Delaminating in preparation for post processing recycling step

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156644, 156646, 156652, 156653, 156657, 1566611, 156668, 156904, 20419232, 427 38, 427 88, 357 65, 430312, 430313, 430317, B44C 122, C03C 1500, C03C 2506, B29C 1708

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046455620

ABSTRACT:
A photolithographic process useful for VLSI fabrication is disclosed for achieving side-wall profile control of poly lines, metal lines, contact and via openings. Layers of a first and second photoresist materials are formed on the poly, metal or oxide-covered substrate. The top layer is patterned by conventional processes to define the final device geometry. The bottom layer is exposed and over-developed to form an overhang structure about the line pattern or the contact/via opening. During the subsequent anisotropic plasma-assisted etching step, some ions or particles are passed obliquely over the overhang and bombard the opening corner, the side-wall and the under-cut area. The plasma-assisted etching step not only forms the poly or metal lines, or the contact or via opening, but also results in an opening with rounded corners and a smoothly tapered side-wall profile. The subsequent metal film deposition step results in a uniform film thickness around the edges of the opening. The process thus alleviates the problem of high contact resistance previously encountered as a result of dry etching the contact or via openings.

REFERENCES:
patent: 4354897 (1982-10-01), Nakajima
patent: 4461672 (1984-07-01), Musser
patent: 4484978 (1984-11-01), Keyser
patent: 4523976 (1985-06-01), Bukhman
IBM Journal of Research and Development, vol. 26, No. 5, Sep. 1982, A. S. Bergendahl et al, "Optimization of Plasma Processing for Silicon Gate FET Manufacturing Applications", pp. 580-589.
Solid State Technology, vol. 22, No. 4, Apr. 1979, P. D. Parry et al, "Antisotropic Plasma Etching of Semiconductor Materials", pp. 125-132.
IBM Technical Disclosure Bulletin, vol. 22, No. 1, Jun. 1979, J. S. Logan et al, "Process for Forming Tapered Vias in SiO.sub.2 by Reactive Ion Etching", pp. 130-132.
Solid State Technology, vol. 27, No. 4, Apr. 1984, J. S. Chang, "Selective Reactive Ion Etching of Silicon Dioxide", pp. 214-219.
IBM Technical Disclosure Bulletin, vol. 22, No. 11, Apr. 1980, K. Chang et al, "Method for Controlling Via Sidewall Slope", pp. 4883-4885.
Patents Abstracts of Japan, vol. 6, No. 9, Jan. 20, 1982.

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