Differential trench open process

Semiconductor device manufacturing: process – Chemical etching – Combined with coating step

Reexamination Certificate

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C438S717000, C438S723000

Reexamination Certificate

active

06207573

ABSTRACT:

BACKGROUND
1. Technical Field
This disclosure relates to semiconductor fabrication and more particularly, to an improved method for opening deep trenches through a relatively thick hard mask by employing a thinner resist layer.
2. Description of the Related Art
In the semiconductor industry, there is a great initiative to provide improved performance from smaller and smaller components. As with all semiconductor devices, semiconductor memories are pushed to the limits of performance. The capabilities of semiconductor memory components are often needed to perform at ever increasing levels from one generation of designs to the next. In one example, a need exists for increasing a capacitance value for deep trenches used for capacitor cells in dynamic random access memories.
Capacitance may be increased for deep trench capacitors by increasing the surface area of the storage node within the deep trench. However, increasing the length or width of the cell impacts the layout area of the semiconductor memory device since each row or column would have to increase by the augmented length and/or width of the new sized trenches. Therefore, this approach is not desirable.
The surface area of the storage node may also be increased by increasing the depth of the trench. This has proven to be a difficult task. The depth of the deep trenches has been limited by a hard mask used to etch the deep trench openings in a substrate.
Referring to
FIG. 1
, a semiconductor memory device
10
includes a substrate
12
, preferably a silicon substrate. A pad stack
14
is deposited on the substrate
12
. Pad stack
14
may include a silicon oxide layer
16
and a nitride layer
18
. A hard mask layer
20
is formed on the pad stack
14
. Hard mask layer
20
may include borosilicate glass, for example. An anti-reflection coating (ARC)
21
is deposited on hard mask layer
20
to assist in patterning a resist layer
22
. Resist layer
22
is formed on ARC layer
21
and patterned over location where a deep trench will be etched in further processing steps. Resist layer
22
is relatively thick ranging from about 600 nm to about 800 nm in thickness. Resist layer
22
is required to be at least 600 nm in thickness to provide a sufficient amount of time to etch hard mask layer
20
and pad stack
14
in later steps.
Referring to
FIG. 2
, an etching process is performed to form a mask for etching substrate
12
to form deep trenches. The conventional process etches through ARC layer
21
, hard mask layer
20
and pad stack
14
. Although etching is selective to resist layer
22
, resist layer
22
is eroded by the etching process and, therefore, a sufficient thickness must be maintained for resist layer
22
. The etching continues until substrate
12
has been reached. Next, resist layer
22
and ARC layer
21
are removed from a top surface of the layer stack as shown in FIG.
3
. This provides hard mask layer
20
on the top surface for etching substrate
12
. It is to be understood that hard mask layer is between 600 nm and 700 nm in thickness. Larger thicknesses are avoided since etching larger thicknesses of hard mask layer
20
would require a thicker resist layer
22
, and the thickness of resist layer
22
is limited by the lithographic process. If resist layer
22
becomes too thin during etching, scalloping occurs in the etched opening due to unavoidable damage on layer
22
by the etching process. This scalloping is undesirable and reduces the hard mask layer
20
thickness and thus reduces the possible depth of the trenches.
Referring to
FIG. 4
, hard mask layer
20
provides a selective etch mask for forming trenches
28
in substrate
12
. Hard mask
20
is eroded during the etching process and therefore sufficient thickness of hard mask layer
20
must be provided. Unfortunately, the thickness of hard mask layer
20
is limited by the lithographic process and the thickness of resist layer
22
, as described above. A hard mask layer that is thicker would require a thicker resist layer
22
. Therefore, the thickness of hard mask layer is limited which results in a depth of trenches
28
which is also limited. Conventional trenches formed into substrate
12
are typically between about 6 microns and about 7 microns-deep for 0.2 micron groundrules. However, deeper trench depth is desirable to increase the capacitance value of trench capacitors to enhance device performance and yield.
Therefore, a need exists for a method for extending the depth of deep trenches in semiconductor devices. A further need exists for providing a method for permitting the use of thicker hard mask layers at a given resist thickness in processing of semiconductors.
SUMMARY OF THE INVENTION
In accordance with the invention, a method for opening holes in semiconductor fabrication includes the steps of providing a pad stack on a substrate, forming a hard mask layer on the pad stack, the hard mask layer selectively removable relative to the pad stack, patterning a resist layer on the hard mask layer, the resist layer being selectively removable relative to the hard mask layer and having a thickness sufficient to prevent scalloping, etching the hard mask layer selective to the resist layer down to the pad stack, and removing the resist layer. After removing the resist layer, the pad stack is etched selective to the hard mask layer such that a hole is opened down to the substrate.
A method for forming deep trenches in semiconductor fabrication includes the steps of providing a pad stack on a substrate, forming a hard mask layer on the pad stack, the hard mask layer selectively removable relative to the pad stack and the hard mask layer having a thickness of greater than about 700 nm, patterning a resist layer on the hard mask layer, the resist layer being selectively removable relative to the hard mask layer and having a thickness sufficient to prevent scalloping, etching the hard mask layer selective to the resist layer down to the pad stack layer, removing the resist layer. After removing the resist layer, the pad stack is etched selective to the hard mask layer such that a hole is opened down to the substrate and etching the substrate to form deep trenches using the hard mask layer as a mask such that the thickness of the hard mask layer enables the deep trenches to be formed to a depth of greater than or equal to 7 microns for 0.2 micron groundrules.
A method for opening holes for contacts in semiconductor fabrication includes the steps of providing a dielectric layer on a target layer, forming a hard mask layer on the dielectric layer, the hard mask layer selectively removable relative to the dielectric layer, patterning a resist layer on the hard mask layer, the resist layer being selectively removable relative to the hard mask layer and having a thickness sufficient to prevent scalloping, etching the hard mask layer selective to the resist layer down to the dielectric layer, removing the resist layer, after removing the resist layer, etching the dielectric layer selective to the hard mask layer such that a hole is opened down to the target layer and depositing a conductive material in the hole such that a contact is formed to the target layer.
In alternate methods, the step of patterning a resist layer may include the step of depositing a resist layer having a thickness of between about 300 nm and about 800 nm. The step of forming a hard mask layer may include the step of forming a hard mask layer having a thickness of between about 700 nm and about 3,000 nm. The hard mask layer may include a selectivity to the resist layer of between about 4 to 1 to about 8 to 1. The pad stack may include a selectivity to the hard mask layer of greater than about 2 to 1. The hard mask layer may include an oxide or a glass and the pad stack may include a nitride. The method may further include the step of applying an anti-reflection coating to the hard mask layer. The deep trenches may be formed to a depth of greater than or equal to 8 microns for 0.2 micron groundrules. The dielectric layer may include a selectivity to the hard mask l

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