Measuring and testing – Gas analysis – Gas chromatography
Patent
1982-04-26
1984-02-21
Kreitman, Stephen A.
Measuring and testing
Gas analysis
Gas chromatography
2504581, 2504591, G01N 3108
Patent
active
044322259
ABSTRACT:
A method and apparatus are described for the quantitative analysis of vaporizable compounds, and in particular of polycyclic aromatic hydrocarbons which may be induced to fluoresce. The sample to be analyzed is injected into a gas chromatography column and is eluted through a narrow orifice into a vacuum chamber. The free expansion of the eluted sample into the vacuum chamber creates a supersonic molecular beam in which the sample molecules are cooled to the extent that the excited vibrational and rotational levels are substantially depopulated. The cooled molecules, when induced to fluoresce by laser excitation, give greatly simplified spectra suitable for analytical purposes. The laser induced fluorimetry provides great selectivity, and the gas chromatograph provides quantitative transfer of the sample to the molecular beam.
REFERENCES:
patent: 4100412 (1978-07-01), Hausdorff
patent: 4350661 (1982-09-01), Davis et al.
Hayes John M.
Small Gerald J.
Albrecht John M.
Besha Richard G.
Kreitman Stephen A.
The United States of America as represented by the United States
Weiss Sandra B.
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