Detection system for a gas chromatograph

Measuring and testing – Gas analysis – Gas chromatography

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Details

2504581, 2504591, G01N 3108

Patent

active

044322259

ABSTRACT:
A method and apparatus are described for the quantitative analysis of vaporizable compounds, and in particular of polycyclic aromatic hydrocarbons which may be induced to fluoresce. The sample to be analyzed is injected into a gas chromatography column and is eluted through a narrow orifice into a vacuum chamber. The free expansion of the eluted sample into the vacuum chamber creates a supersonic molecular beam in which the sample molecules are cooled to the extent that the excited vibrational and rotational levels are substantially depopulated. The cooled molecules, when induced to fluoresce by laser excitation, give greatly simplified spectra suitable for analytical purposes. The laser induced fluorimetry provides great selectivity, and the gas chromatograph provides quantitative transfer of the sample to the molecular beam.

REFERENCES:
patent: 4100412 (1978-07-01), Hausdorff
patent: 4350661 (1982-09-01), Davis et al.

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