Detection and reduction of dielectric breakdown in...

Semiconductor device manufacturing: process – With measuring or testing – Electrical characteristic sensed

Reexamination Certificate

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C438S010000, C438S014000, C438S018000

Reexamination Certificate

active

07943401

ABSTRACT:
Methods for detecting the breakdown potential of a semiconductor device having a thin dielectric layer are disclosed. The method includes measuring a spectroscopy of the thin dielectric layer and determining whether the spectroscopy exhibits the presence of a breakdown precursor (H2, H interstitial radical, H attached radical, and H attached dimer). Preferably, the method is carried out in the presence of a substantially significant applied electric field across dielectric layer. A semiconductor device tested in accordance with this method is also disclosed. Additionally, methods for reducing dielectric breakdown of a semiconductor device having a thin dielectric layer involving the substitution of a second molecule for H2molecules present in the dielectric. This second molecule preferably does not react with Si or O to form an undesired attached state and may be an inert gas having a molecular size approximating that of a Hydrogen atom, such as Helium. A semiconductor device made using this method is also disclosed.

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Wikipedia, Stark effect; “http://en.wikipedia.org/wiki/Stark—effect”.
Encyclopedia Britannica, Stark effect.
Wikipedia, Zeeman effect; “http://en.wikipedia.org/wiki/Zeeman—effect”.
Encyclopedia Britannica, Zeeman effect.

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