Delignification of cellulosic raw materials using acetic acid, n

Paper making and fiber liberation – Processes of chemical liberation – recovery or purification... – Treatment with particular chemical

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162 65, 162 78, 162 81, D21C 320

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053856414

ABSTRACT:
In a three-stage process for the delignification of cellulose-containing raw materials, pulping is initially performed with a solution of concentrated aqueous acetic acid at an elevated temperature and under an elevated pressure. The resultant acetic acid-moist pulp is treated in a second stage with the aforementioned pulping solution with the addition of nitric acid and is then washed or extracted with water or with the pulping solution. In a third treatment stage, the thus-obtained acetic acid-moist pulp is treated with an ozone-containing gas.

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patent: 5074960 (1991-12-01), Nimz et al.
Patt, R., "Application of Nitrogen Dioxide and Ozone in the Pre-Bleaching of Kraft & Sulfite Pulps", 1985 Int'l Pulp Bleaching Conference, pp. 37-44.
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Mbachu, R. A. D. et al.: "The Effect of Acetic and Formic Acid Pretreatment on Pulp Bleaching with Ozone" in the U.S. Book: TAPPI, 1981, vol. 64, No. 1, pp. 67-70.
Nimz, H. H. et al.: "Pulp Production and Bleaching According to the Acetosolv Method" in the German Periodical Das Papier, 1989, Issue 10A, pp. V 102 to V 108.
Wang, D. L.-K. et al.: "Delignification of Spruce and Beech Sulfite Pulps with the Use of Ozone" in the German Periodical Das Papier, 1984 Issue 6, pp. 245-254.
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