Cyclohexenone oxime ether metal salts

Plant protecting and regulating compositions – Plant growth regulating compositions – Organic active compound containing

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504251, 504254, 504260, 504289, 504294, 504295, 546200, 546283, 546284, 548247, 548517, A01N 4340, C07D40500

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06133202&

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BRIEF SUMMARY
The present invention relates to novel cyclohexenone oxime ether metal salts of the formula I ##STR2## where the variables have the following meanings: R.sup.a is C.sub.1 -C.sub.6 -alkyl; transition metal; -C.sub.4 -alkoxy-C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkylthio-C.sub.1 -C.sub.6 -alkyl, a phenoxy-C.sub.1 -C.sub.6 -alkyl, phenylthio-C.sub.1 -C.sub.6 -alkyl, pyridyloxy-C.sub.1 -C.sub.6 -alkyl or pyridylthio-C.sub.1 -C.sub.6 -alkyl group, it being possible for the phenyl and pyridyl rings of these groups to have attached to them, if desired, one to three substituents, in each case selected from the group consisting of nitro, cyano, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkenyloxy, C.sub.3 -C.sub.6 -alkynyl, C.sub.3 -C.sub.6 -alkynyloxy and --NR.sup.g R.sup.h, where C.sub.3 -C.sub.6 -alkynyl, C.sub.1 -C.sub.6 -acyl or benzoyl which, if desired, can have attached to it, in turn, a further one to three radicals, in each case selected from the group consisting of nitro, cyano, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy and C.sub.1 -C.sub.4 -alkythio and C.sub.3 -C.sub.6 -alkynyl; group, it being possible for these groups, if desired, to have attached to them one to three substituents, in each case selected from the group consisting of hydroxyl, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, benzylthio, C.sub.1 -C.sub.4 -alkylsulfonyl and C.sub.1 -C.sub.4 -alkylsulfinyl; contains one or two oxygen or sulfur atoms or one oxygen and one sulfur atom as ring members and which, if desired, can additionally have attached to it one to three substituents, in each case selected from the group consisting of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy and C.sub.1 -C.sub.4 -alkylthio; in addition to carbon atoms, additionally contains one or two oxygen or sulfur atoms or one oxygen and one sulfur atom as ring members and which, if desired, can additionally have attached to it one to three substituents, in each case selected from the group consisting of hydroxyl, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy and C.sub.1 -C.sub.4 -alkylthio; contains one or two nitrogen atoms and one oxygen or sulfur atom, or one to three nitrogen atoms, or one oxygen or one sulfur atom as ring members and which, if desired, can additionally have attached to it one to three substituents, in each case selected from the group consisting of cyano, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkenyloxy, C.sub.3 -C.sub.6 -alkynyloxy and C.sub.1 -C.sub.4 -alkoxy-C.sub.1 -C.sub.4 -alkyl; one to three substituents, in each case selected from the group consisting of nitro, cyano, formyl, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkenyloxy, C.sub.3 -C.sub.6 -alkynyl, C.sub.3 -C.sub.6 -alkynyloxy and --NR.sup.k R.sup.l, where C.sub.3 -C.sub.6 -alkynyl and C.sub.3 -C.sub.6 -alkynyl, C.sub.1 -C.sub.6 -acyl or benzoyl which, if desired, can additionally have attached to it, in turn, one to three substituents, in each case selected from the group consisting of nitro, cyano, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy and C.sub.1 -C.sub.4 -alkylthio; also C.sub.1 -C.sub.6 -alkyl; (C.sub.1 -C.sub.4 -alkyl)ketoxime;
Alk is a C.sub.1 -C.sub.6 -alkylene chain, C.sub.3 -C.sub.6 -alkenylene chain or C.sub.3 -C.sub.6 -alkynylene chain, each of which can have attached to it a methylene group (.dbd.CH.sub.2) and/or one to three substituents, in each case selected from the grou

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The Pesticide Manual, 9th Ed., 1991, pp. 21-22.

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