Crosslinked electrolyte capacitors and methods of making the sam

Details Crosslinked electrolyte capacitors and methods of making the sam Crosslinked electrolyte capacitors and methods of making the sam

1989-11-03

1992-09-08

Griffin, Donald

Electricity: electrical systems and devices

Electrolytic systems or devices

Solid electrolytic capacitor

252578, 29 2503, H01G 306, C08G 6532, H01B 718

Patent

active

051463911

ABSTRACT:
Compact leak-proof electrolytic capacitors including, between the anode and the cathode, an ultrathin layer of a solid electrolyte, are disclosed. The solid electrolyte comprises a solid solution of (a) an alkali metal salt, a transition metal salt, an ammonium salt, an organic ammonium salt, a zinc salt, a cadmium salt, a mercury salt or a thallium salt of (b) a monbasic, dibasic or tribasic acid other than a haloid acid (c) in a polymer of high solvation power. Preferred salts are the tetrafluoroborates and hexafluoroglutarates of sodium and potassium, and the preferred polymer is a blend of polyethylene oxide with a siloxane-alkylene oxide copolymer. Crosslinking of the polymer is accomplished by using an agent which may be a di -, tri, or polyisocyanate, a multifunctional reagent which is an analogue of the compound to be crosslinked or di - and multifunctional acids, or di - and multifunctional amines. Methods of making such capacitors are also disclosed. Rolled solid electrolyte capacitors of this type are characterized by low volume, absence of electrolyte leakage, and minimum dielectric deformation, and are capable of delivering intense bursts of current on demand, thereby being suitable for use in biomedical electronic devices such as cardiac pacemakers and defibrillators implanted in the human body.

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