Copper interconnect structure having stuffed diffusion barrier

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

Reexamination Certificate

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C438S681000, C438S683000, C438S685000, C438S686000, C438S688000

Reexamination Certificate

active

06936535

ABSTRACT:
The present invention provides a method of fabricating a semiconductor device, which could advance the commercialization of semiconductor devices with a copper interconnect. In a process of metal interconnect line fabrication, a TiN thin film combined with an Al intermediate layer is used as a diffusion barrier on trench or via walls. For the formation, Al is deposited on the TiN thin film followed by copper filling the trench. Al diffuses to TiN layer and reacts with oxygen or nitrogen, which will stuff grain boundaries efficiently, thereby blocking the diffusion of copper successfully.

REFERENCES:
patent: 3699734 (1972-10-01), Jacob et al.
patent: 5019531 (1991-05-01), Awaya et al.
patent: 5098860 (1992-03-01), Chakravorty et al.
patent: 5252518 (1993-10-01), Sandhu et al.
patent: 5254498 (1993-10-01), Sumi
patent: 5275973 (1994-01-01), Gelatos
patent: 5391517 (1995-02-01), Gelatos et al.
patent: 5429989 (1995-07-01), Fiordalice et al.
patent: 5592024 (1997-01-01), Aoyama et al.
patent: 5674787 (1997-10-01), Zhao et al.
patent: 5856236 (1999-01-01), Lai et al.
patent: 5892254 (1999-04-01), Park et al.
patent: 5913144 (1999-06-01), Nguyen et al.
patent: 5918150 (1999-06-01), Nguyen et al.
patent: 5939788 (1999-08-01), McTeer
patent: 5985762 (1999-11-01), Geffken et al.
patent: 6008117 (1999-12-01), Hong et al.
patent: 6025269 (2000-02-01), Sandhu
patent: 6037257 (2000-03-01), Chiang et al.
patent: 6107687 (2000-08-01), Fukada et al.
patent: 6120842 (2000-09-01), Lu et al.
patent: 6126806 (2000-10-01), Uzoh
patent: 6127256 (2000-10-01), Matsuno
patent: 6130155 (2000-10-01), Chen et al.
patent: 6130160 (2000-10-01), Vaartstra
patent: 6160314 (2000-12-01), Lee et al.
patent: 6160315 (2000-12-01), Chiang et al.
patent: 6171898 (2001-01-01), Crenshaw et al.
patent: 6204175 (2001-03-01), Lai et al.
patent: 6204179 (2001-03-01), McTeer
patent: 6271136 (2001-08-01), Shue et al.
patent: 6271592 (2001-08-01), Kim et al.
patent: 6342444 (2002-01-01), Higashi et al.
patent: 6380065 (2002-04-01), Komai et al.
patent: 6436825 (2002-08-01), Shue
patent: 6441492 (2002-08-01), Cunningham
patent: 6506668 (2003-01-01), Woo et al.
patent: 0 839 927 (1998-05-01), None
patent: 63299250 (1988-12-01), None
patent: 7326612 (1995-12-01), None
patent: 11003890 (1999-01-01), None
patent: 11111919 (1999-04-01), None
patent: WO 00/75964 (2000-12-01), None
Abstract of presentation to Korean Materials Academic Society, “Improvement of CVD-TiN diffusion barrier performance in Cu metallization by a thin Al interlayer between Cu and TiN,” Apr. 1999, Korea.
Cho, Sung-Lae et al., “Diffusion Barrier Properties of Metallorganic Chemical Vapor Deposited Tantalum Nitride Films Against Cu Metallization,”Journal of the Electrochemical Society, vol. 146, No. 10, pp. 3724-3730 (1999).
Kim, Byoung-Youp et al., “Microstructure and deposition rate of aluminum thin films from chemical vapor deposition with dimethylethylamine alane,”Appl. Phys. Lett., vol. 68, No. 25, pp. 3567-3569 (1996).
Kim, Kyoung-Ho et al., abstract of presentation at Advanced Metallization Conference, Oct. 1999, Orlando, FL. “Improvement of diffusion barrier performance by a thin A1 interlayer deposited between barrier and copper. ”
Kim, Soo-Hyun et al., “A Comparative Study of Film Properties of Chemical Vapor Deposited TiN Films as Diffusion Barriers for Cu Metallization,”Journal of the Electrochemical Society, vol. 146, No. 4, pp. 1455-1460 (1999).
Kim, Yu Chang, “Via Poisoning-Free Dual Damascence Etching for Organic Low-k Material Integration,” Materials Research Society Symposium Spring 2001, Symposium L., L5.5.
Lee, J. et al., “Influence of Vacuum-Annealing on the Diffusion Barrier Properies of MOCVD TiN for Cu Metallization,”Journal of the Korean Physical Society, vol. 35, pp. S65-S70 (1999).
Li, Xiaodong et al., “Structural characterization of aluminum films deposited on sputtered-titanium nitride/silicon substrate by metalorganic chemical vapor deposition from dimethylethylamine alane,”Appl. Phys. Lett, vol. 67, No. 23, pp. 3426-3428 (1995).
Mitsuo, A. et al., “Improvement of high-temperature oxidation resistance of titanium nitride and titanium carbide films by aluminum ion implantation,”Surface and Coatings Technology, vols. 103-104, pp. 98-103 (1998).
Nam, Ki Tae et al., “Improved diffusion barrier by stuffing the grain boundaries of TiN with a thin Al interlayer for Cu metallization,”Applied Physics Letters, vol. 79, No. 16, pp. 2549-2551 (2001).
Nam, Ki Tae et al., “Laterally Segregated Two Phase Mixture Diffusion Barrier for Cu Metallization,” Presentation at Advanced Metallization Conference, Oct. 2, 2001, Tokyo, Japan, Power Point presentation.
Kim, Kyoung-Ho et al., “A novel scheme of CVD-diffusion barrier for Cu metallization,38 D6.6, p. 95 and and Im, Se-Joon et al., A study on CVD TaN as a diffusion barrier for Cu interconnects,” D6.7, pp. 95-96, Presentation at Materials Research Society Symposium—abstracts attached, Apr. 2000, San Francisco.
World-Wide web cubic.mat.ncku.edu.tw/ceramics/homepage/intro-e.htm, “Investigation of Diffusion Barrier of TiAIN Films Between Cu and Si (86),” pp. 7-8 and “Diffusion Barrier and Interface Properties of TiAIN Between Cu and Si (89),” p. 10 (Mar. 29, 2001).
Yoon, L. G. et al., “Improvement of Diffusion Barrier Performance of 10nm TiN layer using a very thin A1interlayer,” Abstract of presentation at Advanced Metallization Conference, Oct. 2000, San Diego, USA.
Gong et al., “Interdiffusion and reaction in the Cu/TiN/Si thin film system,” Applied Surface Science, vol. 92, pp. 335-339, (Dec. 1994).
Rha et al., “Improved TiN film as a diffusion barrier between copper and silicon,” Thin Solid Films, vol. 320, pp. 134-140, (May 4, 1998).

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