Copper bath composition for electroless and/or electrolytic...

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

Reexamination Certificate

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Details

C438S675000, C438S678000, C205S157000, C205S295000, C205S296000

Reexamination Certificate

active

06897152

ABSTRACT:
The present invention is directed to a copper bath composition and a process for the electroless and/or electrolytic plating of copper to fill vias and trenches during the manufacture of integrated circuits. Specifically, the copper bath composition comprises water, copper ions, hydroxide ions, a complexing agent to inhibit the formation of copper oxides, copper hydroxides and copper salts, a stabilizer to control the rate of electroless copper plating, a reducing agent to promote the electroless reduction of the copper ions to copper metal, and a catalyst to promote the electrolytic reduction copper ions to copper metal.

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Hsu, D.T. et al., “Change in chemical state of fluorinated polyimides after the electroless Cu deposition solution treatment”, Journal of Material Science Letters 18 (1999), pp. 1465-1467.

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