Control of crystallite size in diamond film chemical vapor depos

Coating processes – Direct application of electrical – magnetic – wave – or... – Plasma

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427249, 427122, 427577, 428408, 423446, B05D 306, C23C 1626

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active

051696762

ABSTRACT:
In depositing an adhering, continuous, polycrystalline diamond film of optical or semiconductor quality on a substrate, as by forming on the substrate a layer of a refractory nitride interlayer and depositing diamond on the interlayer without mechanical treatment or seeding of the substrate or the interlayer, the substrate is heated in a vacuum chamber containing a microwave activated mixture of hydrogen and a gas including carbon, and the size of deposited diamond crystallites and their rate of deposition selectively varied by a bias voltage applied to the substrate.

REFERENCES:
patent: 4940015 (1990-07-01), Kobashi et al.
patent: 4988421 (1991-01-01), Drawl et al.
patent: 5015494 (1991-05-01), Yamazaki
SDJD/IST--ONR Diamond Technology Initiative Symposium, 11-13 Jul. 1989, pr T5; Office of Naval Research, Washington, D.C.; Lee, Y. H., et al., "Electron controlled CVD of Diamond Thin Films on Various Substrates".
SDJD/IST--ONR Diamond Technology Initiative Symposium, 11-13 Jul. 1989, paper TP11; Office of Naval Research, Washington, D.C.; Tzeng, Y. et al., "Diamond Thin Films Grown by Spiral Hollow Cathode Plasma Assisted Chemical Vapor Deposition".
Applied Physics Letters, vol. 60, No.6, 10 Feb. 1992, pp. 698-700; Stoner, B. R., et al., "Textured Diamond Growth on (100) B-SiC via Microwave Plasma Chemical Vapor Deposition".

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