Conjoint manufacture of MTBE and diisobutylene

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568697, 568699, C07C 4109, C07C 4105

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active

057419515

ABSTRACT:
Methyl tertiary butyl ether and diisobutylene are prepared by reacting methanol with tertiary butyl alcohol to provide an etherification reaction product containing methyl tertiary butyl ether, tertiary butyl alcohol, methanol, isobutylene, and water. A methyl tertiary butyl ether product fraction and an isobutylene fraction are recovered from the etherification reaction product; the isobutylene fraction is charged to an isobutylene conversion reaction zone to form a diisobutylene conversion product, and the diisobutylene conversion product is charged to a diisobutylene distillation zone and separated therein into a lower boiling distillation fraction comprising isobutylene, and diisobutylene and a higher boiling distillation fraction consisting essentially of diisobutylene.

REFERENCES:
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patent: 5243091 (1993-09-01), Kruse et al.
patent: 5292964 (1994-03-01), Gupta
patent: 5354912 (1994-10-01), Hwan et al.
patent: 5386065 (1995-01-01), Kruse et al.
patent: 5387721 (1995-02-01), Kruse et al.
patent: 5395982 (1995-03-01), Cassata et al.

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