Chemical vapor deposition using organometallic precursors

Semiconductor device manufacturing: process – Coating of substrate containing semiconductor region or of... – Insulative material deposited upon semiconductive substrate

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C438S780000, C438S781000, C438S785000

Reexamination Certificate

active

06936549

ABSTRACT:
A multi-component layer is deposited on a semiconductor substrate in a semiconductor process. The multi-component layer may be a dielectric layer formed from a gaseous titanium organometallic precursor, reactive silane-based gas and a gaseous oxidant. The multi-component layer may be deposited in a cold wall or hot wall chemical vapor deposition (CVD) reactor, and in the presence or absence of plasma. The multi-component layer may also be deposited using other processes, such as radiant energy or rapid thermal CVD.

REFERENCES:
patent: 5173327 (1992-12-01), Sandhu et al.
patent: 5203925 (1993-04-01), Shibuya et al.
patent: 5227334 (1993-07-01), Sandhu
patent: 5252518 (1993-10-01), Sandhu et al.
patent: 5254499 (1993-10-01), Sandhu et al.
patent: 5273783 (1993-12-01), Wanner
patent: 5278100 (1994-01-01), Doan et al.
patent: 5376405 (1994-12-01), Doan et al.
patent: 5384289 (1995-01-01), Westmoreland
patent: 5425392 (1995-06-01), Thakur et al.
patent: 5470398 (1995-11-01), Shibuya et al.
patent: 5629229 (1997-05-01), Si et al.
patent: 0 689 249 (1995-06-01), None
patent: WO 93/12538 (1993-06-01), None
patent: WO 93/12542 (1993-06-01), None
Kamada et al., “Structure and Properties of Silicon Titanium Oxide Films Prepared by Plasma CVD Method,” Extended Abstracts of the 1991 Conference on Solid State Devices and Materials, Yokohama,207-209, 1991.
Westmoreland et al., “ Application for Letters Patent—Method of Reducing Carbon Incorporation Into Films Produced by Chemical Vapor Deposition Involving Titanium Organometallicand Metal-Organic Precursor Compounds.”
Green et al., “Chemical Vapor Deposition of Ruthenium and Ruthenium Dioxide Films,” J. Electrochem. Soc., 132(11):2677-2685, Nov., 1985.
Klee, “Spin-On Processing of Perovskite Thin Films for Innovative Microelectronic Devices,” Proc. of the 4thInt. Conf. on Electronic Ceramics & Applications, II:1225-1232, 1994.
Klee et al., .Structural an Electrical Characterization of PZT and PLZT Films Grown on Spin-On Processed Conductive Oxide Electrodes,. Integrated FeIToelectrics, 11:247-258, 1995.
Klee et al., “Deposition of Undoped and Doped Pb (Mg,Nb)O3PbTiO3, PbZrxTi1-xO3, Alkaline Earth Titanate and Layered Perovskite Thin Films on Pt and Conductive Oxide Electrodes by SpinOn Processing: Correlation of Growth and Electrical Properties,” Science and Technology of ElectroceramicThin Films, 284:99-115, 1995.
Krusin-Elbaum and Wittmer, “Conducting Transition Metal Oxides: Possibilities for RuO2 in VLSI Metallization,” J. Electrochem. Soc., 135(10):2610-2614, Oct. 1988.
Sakiyama et al., “Deposition and Properties of Reactively Sputtered Ruthenium Dioxide Films,” J. Electrochem Soc., 140(3):834-839, Mar. 1993.
Vest and Singaram, “Synthesis of Metallo-Organic Compounds for MOD Powers and Films,” Mat. Res. Soc. Symp. Proc., 60:35-42, 1986.
Atsuki et al., “Preparation of Bi-Based Ferroelectric Thim Films by Sol-Gel Method,” Jpn. J. Appl. Phys., 34:5096-5099, Sep. 1995.
Modak and Dey, .Sol-gel processing and characterization of ferroelectric PZT thin-films,. Materials and Processes for Microelectronic Systems, pp. 477-488, R.M. Nair et al., eds. (1990).
Melnick et al., .Process optimization and characterization of device worthy sol-gel based PZT for ferroelectric memories,. FeIToelectrics, 112:329-352 (1990).
Vadimshy and Frankenthal, .Ru and RuO2 as electrical contact materials: preparation and environmental interactions, J. Electrochem Soc., 126(11):2017-2023 (Nov. 1979).
Kolawa et al., .Reactively sputtered RuO2 diffusion barriers,. Appl. Phys. Letr, 50(13):854855 (Mar. 1987).
Kolawa et al., . Microstructure of reactively sputtered oxide diffusion barriers,. J. Electronic Mat. , 17(5):425-432 (1988).
Krusin-Elbaum et al., . Characterization of reactively sputtered ruthenium dioxide for very large scaleJ C18 Sakiyaam et al., . Properties of reactive sputtered RuO2 films and application to diffusion barrier layer in quarter-micron devices,. Jun. 9-10, 1992, VMIC Conference, pp. 317-319.
Krusin-Elbaum and Wittmer, . Conducting transition metal oxides: possibilities for RuO2 in VLSI metallization,. J. Electrochem Soc., 135(10):2610-2614 (Oct. 1988).
Sakiyama et al., .Deposition and properties of reactively sputtered ruthenium dioxide films,. J.Electrochem. Soc., 140(3):834-839 (Mar. 1993).
Pan and Desu, .Reactive ion etching of RuO2 thin films using the gas mixture 02/CF3CFH2,. J. Vac. Sci. Technol. B, 12(6): 3208-3210 (Nov/Dec 1994).
Hrbek et al., “The early stages of ruthenium oxidation,” J. Vac. Sd. Technol. A, 13(3): 14091412 (May/Jun 1995).
Petersson et al., “Silicides of ruthenium and osmium: thin film reactions, diffusion, nucleation, andstability,” J. Appl. Phys., 53(7):4866-4883 (Jul. 1982).
d'Heurle et al., “Rate of formation of silicon dioxide; semiconducting ruthenium silicide,” Appl. Phys.Lett., 47(11):1170-1172 (Dec. 1985).
d'Huerle, F.M., “Formation and oxidation mechanisms in two semiconducting silicides,” Thin Solid Films, 151:41-50 (1987), Elsevier Sequoia Press, Netherlands.
Ryden et al., “Electrical transport properties of IrO2 and RuO2′” Phys. Rev. B, 1(4): 14941500 (Feb. 1970).
Horkans and Shafer, “An Investigation of the Electrochemistry of a Series of Metal Dioxides with RutileType Structure: MoO2, WO2, ReO2′ RuO2′ OSO2′ and IrO2,” J. Electrochem Soc.: Electrochemical Science and Technology, 124(8): 1202-1207, 1977.
Mattheiss, “Electronic Structure of RuO2′ OSO2′ and IrO2,” Physical Review B, 13(6):2433-2450, 1976.
Ryden et al., “High-Field Magnetoresistance of IrO2,” Physical Review B, 6(6):2089-2092, 1972.
Graebner et al., “Magnetothermal Oscillations in RuO2′ OSO2′ and IrO2,” Physical Review B, 13(6):2426 2432, 1976.
Marcus, “Measurement of the Magnetoresistance in the Transition Metal Oxide RuO2′” Physical Letters, 28A(3):191-192,1968.
Marcus and Butler, “Measurement of the De Haas-Van Alphen Effect in the Rutile Structure RuO2′” Physics Letters, 26A(11):518-519, 1968.
Chang and Chou, “Formation and Structure of Epitaxial Ruthenium Silicides on (III)Si,” J. Appl. Phys., 68(5):2411-2414, 1990.
Passenheim and McCollum, “Heat Capacity of RuO2 and IrO2 Between 0.540 and 100K,” The Journal of Ozemical Physics, 51(1):320-321, 1969.
Vining and Allevato, “Progress in Doping of Ruthenium Silicide (Ru2Si3),” Proceedings of the 27thInter society Energy Conversion Engineering Conference, Sand Diego, California, Aug. 37, 1992.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Chemical vapor deposition using organometallic precursors does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Chemical vapor deposition using organometallic precursors, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Chemical vapor deposition using organometallic precursors will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3511602

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.