Chemical vapor deposition of low density silicon dioxide films

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4283191, 427573, 427574, 427579, 427237, 427238, 4272553, 427294, 427314, B05D 306

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active

060542063

ABSTRACT:
A process for producing low-density, porous silica films in a vacuum environment is provided. The films are advantageous for use as low dielectric constant insulating materials in semiconductor devices. In a first step, an organic-group-containing silica precursor is deposited on a semiconductor substrate in a chemical vapor deposition reactor. In a second step, the organic groups are removed by heating in a furnace in an oxidizing environment or by exposure to an oxidizing plasma, thereby creating a low density silica film.

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