Chemical mechanical polishing (CMP) slurry for copper and method

Semiconductor device manufacturing: process – Chemical etching – Combined with the removal of material by nonchemical means

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438691, 438692, 106 3, 106 11, 51304, 51306, 51309, B24B 100

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058973753

ABSTRACT:
A method for chemical mechanical polishing (CMP) a copper layer (22) begins by forming the copper layer (22). The copper layer (22) is then exposed to a slurry (24). The slurry (24) contains an oxidizing agent such as H.sub.2 O.sub.2, a carboxylate salt such as ammonium citrate, an abrasive slurry such as alumna abrasive, an optional triazole or triazole derivative, and a remaining balance of a solvent such as deionized water. The use of the slurry (24) polishes the copper layer (22) with a high rate of removal whereby pitting and corrosion of the copper layer (22) is reduced and good copper interconnect planarity is achieved. This slurry (24) has good selectivity of copper to oxide, and results in copper devices which have good electrical performance. In addition, disposal of the slurry (24) is not environmentally difficult since the slurry (24) is environmentally sound when compared to other prior art slurries.

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Ronald Carpio et al., "Initial study on copper CMP slurry chemistries", 1995 Elsevier Science S.A., Thin Solid Films 266 (1995), pp. 238-244.
S.P. Murarka et al., "Advanced Metallization for Devices and Circuits--Science, Technology and Manufacturability", Mat. Res. Soc. Symposium Proceedings, vol. 337, 1994, pp. 133-138.
J.M.Steigerwald et al., "Mat. Res. Soc. Symp. Proc.," vol. 337, 1994, Method of Chemical Mechanical Polishing Predominantly Copper Containing Metal Layers in Semiconductor Processing, pp. 133-138.

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