Chemical delivery systems and methods of delivery

Dispensing – Processes of dispensing

Reexamination Certificate

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C222S056000

Reexamination Certificate

active

06269975

ABSTRACT:

BACKGROUND
The present invention relates generally to systems and methods for delivering of liquid chemicals, and more particularly, to systems and methods for delivery of liquid chemicals in precise amounts using logic devices and multi-reservoir load cell assemblies.
The present invention has many applications, but may be best explained by considering the problem of how to deliver photoresist to silicon wafers for exposure of the photoresist in the process of photolithography. To form the precise images required, the photoresist must be delivered in precise amounts on demand, be free of bubbles, and be of precise uniform thickness on the usable part of the wafer. The conventional systems have problems as discussed below.
As shown in
FIG. 1
, a representative conventional photoresist delivery system includes supply containers
100
,
102
, typically bottles, which supply photoresist to a single-reservoir
104
by line
117
, which is connected to supply lines
106
,
108
monitored by bubble sensors
110
,
112
and controlled by valves V
1
and V
2
. The bottom of the reservoir is connected to a photoresist output line
114
to a track tool (not shown) which dispenses photoresist on the wafer. The space above the photoresist in the reservoir
104
is connected to a gas line
118
which, based on position of a three-way valve V
3
, either supplies nitrogen gas to the reservoir
104
from a nitrogen manifold line
126
, regulated by needle valve
1
, or produces a vacuum in the reservoir
104
. To sense the level of the photoresist in the reservoir
104
, the system employs an array of capacitive sensors
122
arranged vertically on the walls of the reservoir
104
. A two-way valve V
4
, located between the nitrogen gas manifold and the inlet of a vacuum ejector
124
, supplies or cuts off flow of nitrogen to the vacuum ejector
124
.
The photoresist delivery system must be “on-line” at all times so the track tool can dispense the photoresist as required. Many of the photoresist delivery systems attempt to use the reservoir to provide an on-line supply of photoresist to the track tool, but the photoresist delivery system must still refill the reservoir on a regular basis which is dependent on timely replacement of empty supply containers. Otherwise, the track tool will still fail to deliver the photoresist when demanded.
During dispense mode, when photoresist is withdrawn by the track tool from the reservoir
104
, the valve V
3
permits the nitrogen to flow from the nitrogen manifold to the reservoir
104
to produce a nitrogen blanket over the photoresist to reduce contamination and to prevent a vacuum from forming as the photoresist level drops in the reservoir. Once the photoresist in the reservoir
104
reaches a sufficiently low level the system controller (not shown) initiates refill mode, where a set of problems arise.
During refill mode, the valve V
4
is activated so that nitrogen flows from the manifold line
126
to the vacuum ejector
124
which produces a low pressure line
170
thereby producing a low pressure space above the photoresist in the reservoir
104
. The bubble sensors
110
,
112
monitor for bubbles in the supply lines
106
,
108
, presumed to develop when the supply containers
100
,
102
, become empty. If, for example, the bubble sensor
110
detects a bubble, the controller turns off the valve V
1
to supply container
100
and the valve V
2
opens to supply container
102
to continue refilling the reservoir
104
. However, bubbles in the supply line
106
may not mean supply container
100
is empty. Thus, not all of the photoresist in supply container
100
may be used before the system switches to the supply container
102
for photoresist. Thus, although the conventional system is intended to allow multiple supply containers to replenish the reservoir when needed, the system may indicate that a supply container is empty and needs to be replaced before necessary.
If the supply container
100
becomes empty and the operator fails to replace it and the system continues to operate until the supply container
102
also becomes empty, the reservoir
104
will reach a critical low level condition. If this continues, bubbles may be arise due to photoresist's high susceptibility to bubbles; if a bubble, however minute, enters the photoresist delivered to the wafer, an imperfect image may be formed in the photolithography process.
Further, if the pump of the track tool, connected downstream of the chemical output line
114
, turns on when the reservoir is refilling, the pump will experience negative pressure from the vacuum in the single-reservoir pulling against the pump. Several things can happen if this persists: the lack of photoresist delivered to the track tool may send a false signal that the supply containers are empty, the pump can fail to deliver photoresist to its own internal chambers, lose its prime and ability to adequately dispense photoresist, and the pump can even overheat and burn out. The result of each scenario will be the track tool receives insufficient or even no photoresist, known as a “missed shot,” which impacts the yield of the track tool.
The present invention addresses these problems as well as avoids waste of expensive photoresist, provides a friendly user interface depicting the amount of photoresist remaining in the supply containers, and reduces system capital and operating costs. If, for example, the amount of photoresist in the supply containers cannot be seen, the present invention permits the interface to be provided at a distance by conventional computer network capabilities and the electronics provided.
SUMMARY OF THE INVENTION
The present invention relates to systems using controllers or logic devices and multi-reservoir load cell assemblies for precision delivery of liquid chemicals. It also relates to methods of delivering liquid chemicals from supply sources to processes such that the present invention accurately accounts and adjusts for the dynamic supply and use of the liquid chemical to meet process requirements. Finally, the present invention provides multi-reservoir load cell assemblies for monitoring, regulating, and analyzing the liquid supply available to a process.


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