Catalyzed hydrocarbyllithium process

Details Catalyzed hydrocarbyllithium process Catalyzed hydrocarbyllithium process

1992-02-27

1993-05-18

Dees, Jose G.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07F 102, C07F 302, C07F 304

Patent

active

052118886

ABSTRACT:
A catalytic process for alkylating an alkali metal selected from lithium, sodium and potassium with an alkyl halide containing 3 to 20 carbon atoms comprising conducting the reaction in the presence of a catalytic compound represented by the formula

REFERENCES:
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patent: 3293313 (1966-12-01), Borkowski
patent: 3420903 (1969-01-01), Smith
patent: 4593112 (1986-06-01), Takamizawa
patent: 4814474 (1989-03-01), Shirahata
Journal of Organometallic Chemistry, vol. 326 (1987) pp. 1-7 by Lochmann and Trekoval.
W. Novis Smith, Journal of Organometallic Chemistry, 82, pp. 1-6, Jan. 1969.
A. Shirahata, Tetrahedron Letters, vol. 30, No. 46, pp. 6393-6394, Mar. 1989.

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