Catalyst system for high activity and stereoselectivity in...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C526S161000, C526S160000, C526S170000, C526S943000, C556S051000, C556S052000

Reexamination Certificate

active

11176723

ABSTRACT:
The present invention is directed to a novel composition, and to a method of making the composition, the composition being useful in catalyst systems for the homopolymerization and/or copolymerization of olefins, wherein such catalyst systems display a higher level of activity and stereoselectivity than previously reported. The present invention is also directed to novel polymeric compositions made with such catalyst systems, such as a novel syndiotactic polypropylene that melts at temperatures higher than previously reported.

REFERENCES:
patent: 5055438 (1991-10-01), Canich
patent: 5451649 (1995-09-01), Zenk et al.
patent: 5670680 (1997-09-01), Newman et al.
patent: 6448349 (2002-09-01), Razavi
patent: 6469188 (2002-10-01), Miller et al.
patent: 6613921 (2003-09-01), Campbell et al.
patent: 6693153 (2004-02-01), Miller et al.
patent: 6939928 (2005-09-01), Kawai et al.
patent: 7081493 (2006-07-01), Kawai et al.
patent: 2005/0131171 (2005-06-01), Tohi et al.
patent: 2006/0161013 (2006-07-01), Tohi et al.
patent: 416815 (1991-03-01), None
Miller et al. Organometallics, 2004, 23, 1777-1789.
Razavi, et al., “Syndiotactic Specific Structures, Symmetry Considerations, Mechanistic Aspects”, Organometallic Catalysts and Olefin Polymerization, Berlin (2001), pp. 267-279.
Alt, et al., “Synthese, Charakterisierung und Polymerisationseigenschaften verbückter Haldbsandwichkomplexe des Titans, Zirconiums und Hafniums; Die Molekülstruktur von [C13H8-SiMe2-NtBu]ZrC12”, Journal of Organometallic Chemistry (1999), pp. 21-30, 572.
Andell, et al., “n3-Allyl Complexes of Molybdenum-IV. Preparation and Crystal Structures of Some Substituted-Cyclopentadienyl Molybdenum Allyl Derivatives”, Polyhedron (1989) pp. 203-209, vol. 8 No. 2.
Biagioni, et al., “Reaction of (n5-C13H9)Mn(CO)3 with Alkylphosphines: Formation and Isolation of n1-Fluorenyl Complexes”, Organometallics, (1990), pp. 547-551, 9.
Bochmann, et al., “Synthesis and Structure of [Me2C(C5H4)Flu)Zr(u-H)Cl]2, an n3:n5-Bonded ansa-Metallocene”, Organometallics, (1993) pp. 4718-4720, 12.
Boussie, et al., A Fully Integrated High-Throughput Screening Methodology for the Discovery of New Polyolefin Catalysts: Discovery of a New Class of High Temperature Single-Site Group (IV) Copolymerization Catalysts, J. Am. Chem. Soc., (2003) pp. 4306-4317, 125.
Busico, et al., “Syndiotactic Poly(propylene) from [Me2Si(3,6-di-tert-butyl-9-fluorenyl)(N-tert-butyl)]TiC12-Based Catalysts: Chain-End or Enantiotopic-Sites Stereocontrol?”, Macromoletular Chemistry and Physics, (2003) pp. 1269-1274, 204.
Calderon, et al., “Stereochemically Nonrigid Organometallic Molecules. XXI. The Crystal and Molecular Structures of Tris(cyclopentadienyl)nitrosylmolybdenum”, Journal of the American Chemical Society, (May 7, 1969) pp. 2528-2535, 91:10.
Calhorda, et al., “Exocyclic Coordination of the n3-Fluorenyl Anion: Experimental and Theoretical Study”, Organometallics (1999) pp. 3956-3958, 18.
Calhorda, et al., “Exocyclic coordination of the n3-fluorenyl, n3-cyclopenta[def]-phenathrenyl and n3-8,9-dihydrocyclopenta[def]phenathrenyl anions: X-ray crystal structures, NMR fluxionality and theoretical studies”, New J. Chem., (2002) pp. 1552-1558, 26.
Chien, et al., “Ethylene-Hexene Copolymerization by Heterogeneous and Homogeneous Ziegler-Natta Catalysts and the ‘Commoner’ Effect”, Journal of Polymer Science: Part A: Polymer Chemistry, (1993) pp. 227-237, vol. 31.
Paul James Chirik, Ancillary Ligand Effects on Fundamental Transformations in Metallocene Catalyzed Olefin Polymerization, (2000) pp. 1-231.
Dang, et al., “Simple Route to Bis(3-indenyl)methanes and the Synthesis, Characterization, and Polymerizaiton Performance of Selected racemic-Dichloro[methylenebis(Rn-1-indenyl)]-zirconium Complexes”, Organometallics, (1999) pp. 3781-3791, 18.
Rosa, et al., “Chain Conformation and Unit Cell in the Crystalline Phase of Syndiotactic Poly(4-methyl-1-pentene)”, Macromolecules, (1992) pp. 6938-6942, 25.
Rosa, et al., “Equilibrium Melting Temperature of Syndiotactic Polypropylene”, Macromolecules, (1998) pp. 6206-6210, 31.
Dias, et al., “Preparation of Group 4 metal complexes of a bulky amido-fluorenyl ligand”, Journal of Organometallic Chemistry, (1996) pp. 91-99, 508.
Ewen, et al., “Syndiospecific Propylene Polymerizations with Group 4 Metallocenes”, J. Am. Chem. Soc., (1988) pp. 6255-6256, 110.
Ewen, et al., “Chiral Ansa Metallocenes with Cp Ring-Fused to Thiophenes and Pyrroles: Syntheses, Crystal Structures and Iostactic Polypropylene Catalysts”, J. Am. Chem. Soc., (2001) pp. 4763-4773, 123.
Fierro, et al., “Syndioselective Propylene Polymerization Catalyzed by rac-2,2-Dimethylpropylidene(1-n5-cyclopentadienyl) (1-n5-fluorenyl) dichlorozirconium”, Journal of Polymer Science: Part A: Polymer Chemistry, (1994) pp. 661-673, vol. 32.
Gerkin, et al., “Structure of Fluorene, C13H10, at 159 K”, Acta Cryst., (1984) pp. 1892-1894, C40.
Grisi, et al., “Group 4 Cs Symmetric catalysts and 1-olefin polymerization”, Journal of Molecular Catalysis A: Chemical 140, (1999) pp. 225-233.
Hakansson, et al., “A Crystallographic and Computational Study of a Diethyl Ether Complex of Fluorenyllithium”, Organometallics, (1998) pp. 1208-1214, 17.
Irwin, et al., “A Sterically Expanded ‘Constrained Geometry Catalyst’ for Highly Active Olefin Polymerization and Copolymerization: An Unyielding Comonomer Effect”, J. Am. Chem. Soc., (2004) pp. 16716-16717, 126.
Irwin, et al., “Synthesis and characterization of sterically expanded ansa-n1-fluorenyl-amido complexes”, Polyhedron, (2005) pp. 1314-1324, 24.
Ji, et al., “Kinetics and Mechanism of Substitution Reactions of Mn(n5-C9H7) (CO)3 and Mn(n5-C13H9)(CO)3”, Organometallics, (1984) pp. 740-745, 3.
Kirillov, et al., “[(Cp-CMe2-Flu)2Ln]-[Li(ether)n]+ (Ln = Y, La): Complexes with Unusual Coordination Modes of the Fluorenyl Ligand and the First Examples of Bis-Ansa Lanthanidocenes”, Organometallics, (2003) pp. 4038-4046, 22.
Kowala, et al., “The Crystal and Molecular Structure of (1-5-n-Fluorenyl)(1-3-n-Fluorenyl) dichlorozirconium(IV)”, J.C.S. Chem. Comm., (1974) pp. 993-994.
Lanza, et al., “Energetic, Structural, and Dynamic Aspects of Ethylene Polymerization Mediated by Homogeneous Single-Site ‘Constrained Geometry Catalysts’ in the Presence of Cocatalyst and Solvation: An Investigation at the ab Initio Quantum Chemical Level”, Organometallics, (2002) pp. 5594-5612, 21.
McKnight, et al., “Group 4 ansa-Cyclopentadienyl-Amido Catalysts for Olefin Polymerization”, Chem. Rev., (1998) pp. 2587-2598, 98.
Mejdrich, et al., “Structures of (n1-Fluorenyl)RE(CO)5 and (n5-Fluorenyl)RE(CO)3 and Their Thermal Interconversion in Solid Matrices”, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, (1998) pp. 953-973, 28:6.
Miller, et al., “Highly Stereoregular Syndiotactic Polypropylene Formation with Metallocene Catalysts via Influence of Distal Ligand Substituents”, Organometallics, (2004) pp. 1777-1789, 23.
Mitani, et al., “Fluorine- and Trimethylsilyl-Containing Phenoxy-Imine Ti Complex for Highly Syndiotactic Living Polyproplyenes with Extremely High Melting Temperatures”, J. Am. Chem. Soc., (2002) pp. 7888-7889, 124.
O'Connor, et al., “Ring-Slippage Chemistry of Transition-Metal Cyclopentadienyl and Idenyl Complexes”, Chem. Rev., (1987) pp. 307-318, 87.
Okuda, et al., “Synthesis and Characterization of Zirconium Complexes Containing a Linked Amido-Fluorenyl Ligand”, Organometallics, (1995) pp. 789-795, 14.
Razavi, et al., “Preparation and crystal structures of the complexes (n5-C5H3TMS-CMe2-n5-C13H8)MC12 and [3,6-ditButC13H6-SiMe2-NtBu]MC12 (M = Hf, Zr or Ti): mechan

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Catalyst system for high activity and stereoselectivity in... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Catalyst system for high activity and stereoselectivity in..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Catalyst system for high activity and stereoselectivity in... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3799073

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.