Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Mixture is exhaust from internal-combustion engine
Patent
1996-03-14
1999-09-07
Yildirim, Bekir L.
Chemistry of inorganic compounds
Modifying or removing component of normally gaseous mixture
Mixture is exhaust from internal-combustion engine
4232132, 4232391, 502304, 502326, 502330, B01J 2363, B01J 2358
Patent
active
059483768
ABSTRACT:
A catalyst for purifying exhaust gases includes a porous support, an NO.sub.x storage component including at least one member selected from the group consisting of alkaline-earth metals, rare-earth elements and alkali metals, and loaded on the porous support, a noble metal catalyst ingredient loaded on the porous support, and disposed adjacent to the NO.sub.x storage component, and ceria (CeO.sub.2) disposed away from the noble metal catalyst ingredient. By disposing the noble metal catalyst ingredient adjacent to the NO.sub.x storage component, the reduction reactions of NO.sub.x can be facilitated in fuel-rich (i.e., oxygen-lean) atmospheres without being interfered by the ceria. By disposing the ceria away from the noble metal catalyst ingredient, oxygen, which has been stored thereon in fuel-lean (i.e., oxygen-rich) atmospheres, can be released from the ceria at a controlled rate in a controlled amount in fuel-rich (i.e., oxygen-lean) atmospheres, and thereby the released oxygen can be inhibited from reacting with HC and CO in fuel-rich (i.e., oxygen-lean) atmospheres. Thus, the catalyst is improved in terms of NO.sub.x purifying performance.
REFERENCES:
patent: 4369132 (1983-01-01), Kinoshita et al.
patent: 4426365 (1984-01-01), Magder
patent: 4678770 (1987-07-01), Wan et al.
patent: 4931419 (1990-06-01), Blanchard et al.
patent: 5388406 (1995-02-01), Takeshima et al.
Ishibashi Kazunobu
Kasahara Koichi
Miyoshi Naoto
Tanizawa Tuneyuki
Tateishi Syuji
Cataler Industrial Co. Ltd.
Toyota Jidosha & Kabushiki Kaisha
Yildirim Bekir L.
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