Catalyst composition

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Inorganic carbon containing

Reexamination Certificate

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C546S002000, C526S145000

Reexamination Certificate

active

07820582

ABSTRACT:
This invention relates to catalyst compounds, catalysts systems and methods to oligomerize or polymerize monomers where the catalyst compound and the catalyst system comprise compounds of formula: LMX2or (LMX2)2wherein: M is a Group 7, 8, 9, 10 or 11 transition metal; L is a tridentate or tetradentate neutrally charged ligand that is bonded to M by at least three nitrogen atoms; at least one of the nitrogen atoms is a central non-pyridinal nitrogen atom and is not bonded to its adjacent atoms by a multibond; at least two of the nitrogen atoms are terminal nitrogen atoms; at least one terminal nitrogen atom is part of a pyridinyl ring; at least one other terminal nitrogen atom is substituted with at least one C3-C50hydrocarbyl or halobydrocarbyl; the central nitrogen atom is bonded to at least two different carbon atoms; and each X is an anionic monodentate ligand.

REFERENCES:
patent: 3651065 (1972-03-01), Yagi et al.
patent: 3723553 (1973-03-01), Wu et al.
patent: 5880241 (1999-03-01), Brookhart et al.
patent: 6689848 (2004-02-01), Nagy et al.
patent: 6809058 (2004-10-01), Boffa et al.
patent: 7217675 (2007-05-01), Solan et al.
patent: 2003/0166806 (2003-09-01), Nagy et al.
patent: 2004/0242893 (2004-12-01), Solan et al.
patent: 2004/0266961 (2004-12-01), Solan et al.
patent: 2007/0066776 (2007-03-01), Solan et al.
patent: WO 99/02472 (1999-01-01), None
patent: WO 99/12981 (1999-03-01), None
patent: WO 00/58320 (2000-05-01), None
patent: WO 00/50470 (2000-08-01), None
patent: 00/68280 (2000-11-01), None
patent: WO 01/14391 (2001-03-01), None
patent: WO 01/83571 (2001-11-01), None
patent: 03/076481 (2003-09-01), None
Kooistra et al. Eur. J. Inorg. Chem., 2003, 648-655.
He te al., J. Chem. Soc., Dalton Trans., 2002, 4224-4235.
Weitzer et al., J. Chem. Soc., Dalton Trans., 2002, 686-694.
Prokopchuk et al., “Methyl(hydrido)platinum(IV) Complexes with Flexible Tridentate Nitrogen-Donor Ligands”,Organometallics, vol. 22, pp. 787-796, (2003).
Markies et al., “Synthesis and Structural Studies of Ionic Monoorganopalladium(II) Complexes with Tridentate Nitrogen-Donor Ligands,”Organometallics, vol. 13, pp. 3244-3258, (1994).
Johnson et al., “Cooper ATRP Catalysts with Quadridentate Amine Ligands: The Effects of Steric and Electronic Tuning on the Polymerization of Methyl Methacrylate,”Macromolecules, vol. 33, pp. 8618-8628, (2000).
Dey et al., “Crystal Structure and Magnetic Interactions in Nickel(II) Dibridged Complexes Formed by Two Azide Groups or by Both Phenolate Oxygen-Azide, -Thiocyanate,-Carboxylate, or-Cyanate Groups,”Inorganic Chemistry, vol. 43, pp. 2427-2434, (2004).
Britovsek et al., “Oligomerisation of Ethylene by Bis(imino)pyridyliron and -cobalt Complexes”,Chem. Eur. J., vol. 6, No. 12, pp. 2221-2231 (2000).
Britovsek et al., “Bis(imino)pyridyl iron and cobalt complexes: the effect of nitrogen substituents on ethylene oligomerisation and polymerisation,”J. Chem. Soc., Dalton Trans., pp. 1639-1644, (2001).
Britovsek et al., “The role of bulky substituents in the Polymerization of ethylene using late transition metal catalysts: a comparative study of nickel and iron catalyst systems,”Inorganica Chimica Acta, vol. 345, pp. 279-291, (2003).
Small et al., Iron Based Catalysts with Exceptionally High Activities and Selectivities for Oligomerization of Ethylene to Linear α-Olefins,J. Am. Chem. Soc., vol. 120, pp. 7143-7144, (1998).
B. Elvers, et al., Ed. Ullmann's Encyclopedia of Industrial Chemistry, vol. A13, VCH Verlagsgesellschaft mbH, Weinheim, pp. 243-247 and 275-276, (1989).
Weitzer et al., “Low Temperature Stopped-flow Studies in Inorganic Chemistry”, Journal of the Chemical Society, Dalton Transactions, 2002, pp. 686-694.
Wang et al., “Late Transition Metal Complexes bearing 2,9-bis(imino)-1,10-phenanthrolinyl Ligands: Synthesis, Characterization and their Ethylene Activity”, Journal of Organometallic Chemistry 658 (2002) pp. 62-70.
Kobayashi et al., “Release of free Nucleobases from Oligomers by Copper(II)-Peroxide Adduct”, Polyhedron, 19, 2000, pp. 2639-2648.
Kooistra et al., “Cobalt Chloride Complexes of N3and N4Donor Ligands”, Eur. J. Inorg. Chemistry, 2003, pp. 648-655.

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