Catalyst composition

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Organic compound containing

Reexamination Certificate

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Details

C502S103000, C526S160000, C526S164000, C526S165000, C526S134000, C526S340000

Reexamination Certificate

active

10233593

ABSTRACT:
A catalyst composition for polymerization of a conjugated diene or copolymerization of a conjugated diene and an aromatic vinyl compound, which comprises the following components: (A) a metallocene-type complex of a rare earth metal compound (samarium complex etc.), and (B) an ionic compound composed of a non-coordinate anion and a cation (triphenylcarbonium tetrakis(pentafluorophenyl)borate etc.) and/or an aluminoxane. The catalyst composition is useful for producing a polymer having a high cis-1,4-configuration content in the microstructure and a narrow molecular weight distribution.

REFERENCES:
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patent: 5563219 (1996-10-01), Yasuda et al.
patent: 5670587 (1997-09-01), Takeuchi et al.
patent: 5744415 (1998-04-01), Wenzel
patent: 6124410 (2000-09-01), Ito et al.
patent: 6310164 (2001-10-01), Morizono et al.
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patent: 0 667 357 (1995-08-01), None
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patent: 8-245711 (1996-09-01), None
patent: 10-324707 (1998-12-01), None
patent: WO 97/42160 (1997-11-01), None
“Stereospecific Polymerization of 1,3-Butadiene with Samarocene-Based Catalysts”, Macromolecules, 1999, 32, 9078-9079.

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