Bridged carboxylic ortho ester sweetener

Food or edible material: processes – compositions – and products – Products per se – or processes of preparing or treating... – Noncarbohydrate sweetener or composition containing same

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549363, A23L 1236, C07D31914

Patent

active

052982726

ABSTRACT:
A sugar substitute which is identified as N-(L)-aspartyl-1-(1'-aminoethyl)-4-methyl-2,6,7-trioxabicyclo[2,2,2]octane . The compound is a bridged carboxylic ortho ester which has an intense sweet taste and is suitable for use as a sugar substitute.

REFERENCES:
Mazur, R. H., "Discovery of Aspartame," Food Sci. and Technol, 1984, 12, 3.
Mazur, R. H., Schlatter, J. M., Goldkamp, A. H., "Structure-Taste Relationships Of Some Dipeptides," J. Am. Chem. Soc., 1969, 91, 2684.
Grenby, T. H. (Ed.), Progress In Sweeteners, pp. 1-46, Elssevier Applied Science, London, New York.
Goodman, M., Coddington, J., Mierke, D. F., Fuller, W. D., "A Model For The Sweet Taste Of Stereoisomeric Retro-Inverso And Dipeptide Amides," J. Am. Chem. Soc. 1987, 109, 4712.
Goodman, M.; Miercke, D. F., Fuller, W. D., "A Stereoisomeric Approach To The Molecular Basis Of Taste Of Retro-Inverso And Dipeptide Amides," Proceedings Of The Japan Symposium On Peptide Chemistry, T. Shiba, S. Sakakibara (Eds.), Protein Research Foundation, Japan 1988, pp. 699-704.
Mazur, R. H., Reuter, J. A., Swiatek, K. A., And Schlatter, J. M., "Synthetic Sweetners.3. Aspartyl Dipeptide Esters From L- and D-Alkylglycines," J. Med. Chem., 1973, 16, 11.

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