Block copolymers of acrylate and methacrylate units

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525 73, 525 80, 525 93, 525 94, 525302, C08L 5104, C08L 5300

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053996208

ABSTRACT:
Linear, star or dendrimeric block copolymers are composed of from 10 to 90% by weight of at least one block of one or more acrylates of an alcohol of 1 to 8 carbon atoms and from 10 to 90% by weight of at least one block of one or more methacrylates of an alcohol of 1 to 8 carbon atoms, each block having a number average molecular weight of from 1,000 to 100,000 g/mol and the quotient M.sub.w /M.sub.n (weight average
umber average) of each block being less than 2, and said block copolymers may be blended with styrene copolymers or acrylate copolymers and, if required, acrylate rubbers.

REFERENCES:
patent: 4524196 (1985-06-01), Farnham et al.
patent: 4794144 (1988-12-01), Spinelli
patent: 4831079 (1989-05-01), Ting
Gunesin et al., "Block Copolymers Obtained . . . ", Sep. 1981, vol. 26, No. 9, 2296, J. of Applied Poly. Science.
Macromolecules, vol. 21, No. 9, Sep. 1988 pp. 2892-2894.
Macromolecular, vol 20 1987-pp. 1473-1488.
Macromolecules, vol. 17, 1984, pp. 1417-1419.
Journal of the American Chemical Society, vol. 105, 1983 pp. 5706-5708.
Polymer Preprints vol. 18, No. 1, Mar. 1977 686-693.
Polymer Preprints vol. 32, No. 1, Apr. 1991 299.

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