Bicycloalkanes

Details Bicycloalkanes Bicycloalkanes

1972-12-22

1977-02-15

Sutto, Anton H.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260338, 2603405, 2603409, 260464, 260465D, 260468G, 260488B, 260586F, 260590FA, 260586C, C07D31912, A01N 928

Patent

active

040082539

ABSTRACT:
Bicycloalkane derivatives of the formula ##STR1## WHEREIN N IS 1 OR 2, R.sub.1 is lower alkyl, X is free or ketalized carbonyl or a free, esterified, or etherified hydroxymethylene, and Y is --S--R.sub.2, --SO.sub.m --R.sub.2, or ##STR2## wherein m is 1 or 2, R.sub.2 is alkyl, aryl, or aralkyl, R.sub.3 is hydrogen or lower alkyl, R.sub.4 is alkoxycarbonyl, or acyl or phenyl optionally substituted with lower alkoxy or benzyloxy- or acyloxy; and Z is nitrile, nitro, lower alkoxycarbonyl, lower alkanoyl, lower alkylsulfinyl, or lower alkylsulfonyl are useful intermediates in the total synthesis of steroids. The compounds are prepared by reacting a corresponding compound lacking the CH.sub.2 Y substituent with formaldehyde and a mercaptan or a sulfinic acid, followed if desired by oxidation and optional salt condensation.

REFERENCES:
patent: 3644429 (1972-02-01), Hajos et al.

Affiliated with

Also associated with

Rating

Bicycloalkanes does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Bicycloalkanes, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Bicycloalkanes will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-1437642