Aqueous developable photopolymer compositions containing terpoly

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Radiation sensitive composition or product or process of making

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430281, 430286, 430288, 430906, 430908, 430910, G03C 168

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active

043616402

ABSTRACT:
Compatible, aqueous developable photopolymerizable composition consisting essentially of (a) 22 to 32% by wt. of a monomeric compound having at least two terminal ethylenic groups, (b) 0.1 to 5.0% by wt of a photoinitiator or initiator system, (c) 40 to 80% by wt of a binder system which is the reaction product of (1) 65 to 87 parts by wt of a terpolymer of methylmethacrylate, butylmethacrylate and methacrylic acid as defined, (2) 5 to 20 parts by wt of a polyamide resin and (3) 5 to 20 parts by wt of a copolymer of vinyl pyrrolidone and vinyl acetate, (d) 0.03 to 0.10% by wt of a thermal polymerization inhibitor, and optionally up to 18% by wt of a plasticizer and up to 2.0% by wt of a tertiary amine capable of salt formation with a carboxylic acid. Aqueous developable photopolymerizable elements comprise a support bearing a layer of the composition. Relief printing plates can be prepared by imagewise exposing and developing the elements.

REFERENCES:
patent: 3804631 (1974-04-01), Faust
patent: 4019972 (1977-04-01), Faust
patent: 4189322 (1980-02-01), Hoffmann et al.

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