Apparatus and method to improve resist line roughness in...

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Making electrical device

Reexamination Certificate

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C430S314000, C430S950000

Reexamination Certificate

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07018779

ABSTRACT:
A process for prohibiting amino group transport from the top surface of a layered semiconductor wafer to a photoresist layer introduces a thin film oxynitride over the silicon nitride layer using a high temperature step of nitrous oxide (N2O) plus oxygen (O2) at approximately 300° C. for about 50 to 120 seconds. By oxidizing the silicon nitride layer, the roughness resulting from the adverse affects of amino group transport eliminated. Moreover, this high temperature step, non-plasma process can be used with the more advanced 193 nanometer technology, and is not limited to the 248 nanometer technology. A second method for exposing the silicon nitride layer to an oxidizing ambient, prior to the application of antireflective coating, introduces a mixture of N2H2and oxygen (O2) ash at a temperature greater than or equal to 250° C. for approximately six minutes. This is followed by an O2plasma clean and/or an Ozone clean, and then the subsequent layering of the ARC and photoresist.

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Derwent Abstract of TW 441002, “Metal interconnect production comprises forming dielectric layer on sustrate having copper wire, and forming contact opening and trench in dielectric layer to expose surface of cooper wire”, Chen et al., Jun. 2001.

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