Drying and gas or vapor contact with solids – Process – Gas or vapor contact with treated material
Reexamination Certificate
2000-11-20
2003-09-30
Esquivel, Denise L. (Department: 3749)
Drying and gas or vapor contact with solids
Process
Gas or vapor contact with treated material
C034S493000, C034S497000, C034S527000, C034S228000, C134S061000, C134S137000, C134S902000
Reexamination Certificate
active
06625901
ABSTRACT:
BACKGROUND
The present invention relates to an apparatus and a method for drying a substrate and more particularly, to an apparatus and a method for drying a disk for a data storage device (hard drive) by controlled delivery of polar organic vapor, such as isopropyl alcohol (IPA), acetone, or methanol.
In the manufacture of LCD (liquid crystal display) panels, and hard drives, it is necessary to clean and dry the substrates for the above products, such as glass substrates, and disks, during the manufacturing process. The purpose of drying the substrates is to remove water on the substrates after cleaning. Currently several drying methods have been used in electronic component industry. The methods include the spin-rinse dry method, the hot water slow pull method, the Marangoni-type process, and the hot IPA process.
The spin-rinse dry uses centrifugal forces to remove water from substrate surfaces. However, spin-rinse dry is known to have problems such as water spotting, static electric charge build-up, and stress-induced substrate damage.
In the hot water slow pull method, the substrates are immersed in a hot water bath, which is heated to 80-90° C., and then slowly pulled from the bath. When a substrate is pulled from the bath, a thin water film is formed on the surface of the substrate. Then, the thermal energy stored in the substrate evaporates the thin water film. For successful evaporation, the rate at which the substrate is separated from the bath must be matched to the evaporation rate. The hot water process has several shortcomings. When the substrate has a non-homogeneous surface, partly hydrophobic and partly hydrophilic, the substrate is likely to have stains thereon. Further, condensation of water vapor on the substrate after the substrate is pulled from the hot water may produce stains on the substrate.
The hot IPA process uses a large quantity of IPA, which is flammable, to fill the drying chamber. Accordingly, the hot IPA process is costly and environmentally unsafe.
The Marangoni-type process involves the introduction of a polar organic compound which dissolves in the liquid and thereby reduces the surface tension of the liquid. U.S. Pat. No. 6,027,574, entitled “METHOD OF DRYING A SUBSTRATE BY LOWERING A FLUID SURFACE LEVEL”, shows a Marangoni-type process. According to the Maringoni principle, fluid flows from low surface tension region to high surface tension region. In the Marangoni-type process, while the substrate is separated from the bath containing water that is at room temperature, the water is driven away from the substrate because of the Marangoni effect. To avoid condensation of water vapor on the surface of the substrate, the Marangoni-type process does not use hot water.
There are several issues with conventional Marangoni-type process. First, the drying speed of the process is low, because the substrate is dried at room temperature, and the chamber is purged of the remaining IPA vapor for an extended period of time (3-5 minutes) after being removed from the water. Accordingly, drying cost is high. Second, although room temperature water is used, there is still a condensation problem during and after the separation of the substrate from the water. Water vapor condenses on the substrate and forms micro droplets that leave a residue behind, causing defects in subsequent manufacturing processes. Fourth, purging of IPA while the substrate is dried in the chamber may cause condensation of water vapor.
Accordingly, an effective drying process should be cost-effective by increasing drying speed, and should be environmentally safe, and should prevent the condensation of water on the substrate.
SUMMARY
An aspect of the present invention provides a substrate dryer. A dryer in accordance with an embodiment of the present invention includes: a bath containing a fluid; a fluid heater that heats the fluid; a chamber; and a delivery system for supplying a polar organic vapor, such as isopropyl alcohol. The isopropyl alcohol delivery system supplies isopropyl alcohol vapor to an interface between the substrate and the fluid when the substrate is removed from the fluid of the bath into the chamber. The interface is the boundary between a portion of the substrate out of the fluid and a portion of the substrate in the fluid.
The isopropyl alcohol vapor may be combine with a carrier gas, such as nitrogen. In addition, the isopropyl alcohol delivery system supplies the isopropyl alcohol vapor from one or more directions.
The dryer further includes a chamber environment control system that supplies a heated gas into the chamber to dry the substrate and exhaust the remaining isopropyl alcohol vapor and water vapor. The chamber environment control system includes: a gas inlet through which the gas is supplied into the chamber; a gas outlet through which the gas is removed out of the chamber; and a gas heater that heats the gas before the gas is supplied into the chamber. The chamber environment control system controls the temperature and humidity in the chamber. The gas inlet is at a top portion of the chamber, and the gas outlet is at the bottom portion of the chamber. Further, a variable speed fan is connected to the gas outlet to draw the gas from the chamber.
The dryer further includes a fluid circulation system that circulates the fluid in the bath and a substrate transfer system that transfers the substrate into and out of the fluid of the bath. The fluid circulation system includes: a pump circulating the fluid into and out of the bath; and a filter through which the fluid from the bath passes before being supplied into the bath. The substrate transfer system includes: a nest containing the substrate therein; and an arm that moves so that the substrate in the nest is immersed into and removed from the fluid of the bath.
The dryer further includes: a chamber heater attached to the chamber to transfer thermal energy into the chamber and an overflow tank receiving overflow of the fluid from the bath.
Another aspect of the present invention provides a method of drying a substrate. A drying method in accordance with an embodiment of the present invention includes: immersing a substrate into a fluid contained in a bath; removing the substrate from the fluid into a chamber; and supplying a polar organic vapor, such as isopropyl alcohol vapor, to an interface between the substrate and the fluid. Introduction of the isopropyl alcohol vapor forms a thin layer of mixture of isopropyl alcohol vapor and water at the interface, increasing the wettability of non-homogeneous substrates and promoting removal of the fluid when the substrate is removed from the fluid. The fluid in the bath has a temperature higher than the room temperature
The method further includes: supplying a gas into the chamber to dry the substrate; heating the gas before supplying the gas into the chamber; and removing the gas. While the gas is removed, the water vapors evaporated from the fluid and the remaining IPA vapor are also removed.
The method further includes: circulating the fluid into and out of the bath; heating the fluid; and filtering the fluid before the fluid is supplied into the bath. The method further includes heating the chamber to transfer thermal energy into the chamber.
REFERENCES:
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patent: 5569330 (1996-10-01), Schild et al.
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patent: 5911837 (1999-06-01), Matthews
patent: 6027574 (2000-02-01), Fishkin et al.
patent: 6132811 (2000-10-01), Schellenberger et al.
Mehmandoust Yassin
Stephens Donald E.
DuLin, Esq Jacques M.
Esquivel Denise L.
Innovation Law Group, Ltd.
O'Malley Kathryn S.
Oliver Design, Inc.
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