Apparatus and method for diamond production

Single-crystal – oriented-crystal – and epitaxy growth processes; – Forming from vapor or gaseous state – With decomposition of a precursor

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C117S084000, C117S092000, C117S102000

Reexamination Certificate

active

11043062

ABSTRACT:
An apparatus for producing diamond in a deposition chamber including a heat-sinking holder for holding a diamond and for making thermal contact with a side surface of the diamond adjacent to an edge of a growth surface of the diamond, a noncontact temperature measurement device positioned to measure temperature of the diamond across the growth surface of the diamond and a main process controller for receiving a temperature measurement from the noncontact temperature measurement device and controlling temperature of the growth surface such that all temperature gradients across the growth surface are less than 20° C. The method for producing diamond includes positioning diamond in a holder such that a thermal contact is made with a side surface of the diamond adjacent to an edge of a growth surface of the diamond, measuring temperature of the growth surface of the diamond to generate temperature measurements, controlling temperature of the growth surface based upon the temperature measurements, and growing single-crystal diamond by microwave plasma chemical vapor deposition on the growth surface, wherein a growth rate of the diamond is greater than 1 micrometer per hour.

REFERENCES:
patent: 5099788 (1992-03-01), Ito et al.
patent: 5209182 (1993-05-01), Ohta et al.
patent: 5704976 (1998-01-01), Snail
patent: WO 01/31082 (2003-03-01), None
B.V. Spitsyn et al., “Vapor Growth of Diamond on Diamond and Other Surfaces”, Journal of Crystal Growth 52 (1981) pp. 219-226.
Mutsukazu Kamo et al., “Diamond Synthesis From Gas Phase in Microwave Plasma”, Journal of Crystal Growth 62 (1983) pp. 642-644.
Jean-Pierre Vitton et al., “High Quality Homoepitaxial Growth of Diamond Films”, Diamond and Related Materials, 2 (1993) pp. 713-717.
G.Z. Cao et al., “Growth of {100} Textured Diamond Films by the Addition of Nitrogen” Journal of Applied Physics, vol. 79, No. 3, Feb. 1, 1996, pp. 1357-1364.
S. Jin et al., “Effect of Nitrogen on the Growth of Diamond Films”, Applied Physics Letters, vol. 65, No. 4, Jul. 25, 1994, pp. 403-405.
W. Müller-Sebert et al., “Nitrogen Induced Increase of Growth Rate in Chemical Vapor Deposition of Diamond” Applied Physics Letters. vol. 68, No. 1, Jan. 1, 1996, pp. 759-760.
A. Afzal et al., “HFCVD Diamond Grown With Added Nitrogen: Film Characterization and Gas-Phase Composition Studies”, Diamond and Related Materials 7 (1998) pp. 1033-1038.
Dr. R.S. Sussmann, A New Diamond Material for Optics & Electronics, IDR Feb. 1993 New Products. pp. 63-72.
X. Jiang et al., “The Coalescence of [001] Diamond Grains Heteroepitaxially Grown on (001) Silicon” Applied Physics Letters, vol. 69, No. 24, Dec. 9, 1996, pp. 3902-3904.
M. Schreck et al., “Diamond Nucleation on Iridium Buffer Layers and Subsequent Textured Growth: A Route for the Realization of Single-Crystal Diamond Films” Applied Physics Letters, vol. 78. No. 2, Jan. 8, 2001, pp. 192-194.
Chih-Shiue Yan et al., “Multiple Twinning and Nitrogen Defect Center in Chemical Vapor Deposited Homoepitaxial Diamond” Diamond and Related Materials 8 (1999), pp. 2022-2031.
M.A. Tamor et al., “On the role of penetration twins in the morphological development of vapor-grown diamond films”, Journal of Materials Research, vol. 9, No. 7, Jul. 1994, pp. 1839-1848.
R.E. Stallcup II et al., “Scanning Tunneling Microscopy Studies of Temperature-Dependent Etching of Diamond (100) by Atomic Hydrogen” Physical Review Letters, vol. 86, No. 15, Apr. 9, 2001, pp. 3368-3371.
Yogesh K. Vohra et al., “Resonance Raman and photoluminescence investigations of micro-twins in homoepitaxially grown chemical vapor deposited diamond”, Applied Physics Letters, vol. 71, No. 3, Jul. 21, 1997, pp. 321-323.
J. te Nijenhuis et al., “Red luminescence in phosphorous-doped chemically vapor deposited diamond”, Journal of Applied Physics, vol. 82 (1), Jul. 1, 1997, pp. 419-422.
Mikka Nishitani-Gamo et al., “Confocal Raman spectroscopic observation of hexagonal diamond formation from dissolved carbon in nickel under chemical vapor conditions” Applied Physics Letters, vol. 73, No. 6, Aug. 10, 1998, pp. 765-767.
C.F.O Graeff et al. “Optical excitation of paramagnetic nitrogen in chemical vapor deposited diamond”, Applied Physics Letters, vol. 69, No. 21, Nov. 18, 1996, pp. 3215-3217.
A.T. Collins, “Vacancy enhanced aggregation of nitrogen in diamond”, J. Phys. C: Solid St. Phys., 13 (1980), pp. 2641-2650.
Alan T. Collins et al., “Color changes produced in natural brown diamonds by high-pressure, high-temperature treatment”, Diamond and Related Materials 9 (2000), pp. 113-122.
Isao Sakaguchi et al., “Suppression of surface cracks on (111) homoepitaxial diamond through impurity limitation by oxygen addition”, Applied Physics Letters, vol. 73, No. 18, Nov. 2, 1998, pp. 2675-2677.
Y. Liou et al., “The effect of oxygen in diamond deposition by microwave plasma enhanced chemical vapor deposition”, Journal of Materials Research, vol. 5, No. 11, Nov. 1990, pp. 2305-2312.
C. Wild et al., “Oriented CVD diamond films: twin formation, structure and morphology”, Diamond and Related Materials, 3 (1994) pp. 373-381.
Chih-Shiue Yan et al., “Very high growth rate chemical vapor deposition of single-crystal diamond”, vol. 99 (Oct. 1, 2002) pp. 12523-12525.
Ji-an Zu et al., Moissanite: A Window for High-Pressure Experiments, Science vol. 290, Oct. 27, 2000, pp. 783-785.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Apparatus and method for diamond production does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Apparatus and method for diamond production, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Apparatus and method for diamond production will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3827322

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.