Aluminoxane synthesis employing reduced amount of trialkylalumin

Organic compounds -- part of the class 532-570 series – Organic compounds – Aluminum containing

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556180, 556187, 526160, 526943, 502103, 502117, 502152, C07F 506

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060463473

ABSTRACT:
A catalytically active aluminoxane can be synthesized from a precursor formed by the combination of at least one trialkylaluminum compound and at least one organoaluminum compound containing a carbon-oxygen bond therein, such as an alkoxy group-containing organoaluminum compound of the formula (CH.sub.3).sub.2 Al--O--R, where R is alkyl.

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Comprehensive Organometallic Chemistry II, E.W. Abel et al., eds., Pergamon, Elsevier Science Inc., Tarrytown, NY, 1995, vol. 1, pp. 452 and 498-499.
S. Pasynkiewicz, "Alumoxanes: Synthesis, Structures, Complexes and Reactions", Polyhedron, vol. 9, No. 2/3, pp. 429-453 (1990).
S. Pasynkiewicz, "Some Reactions of Alumoxanes", Macromol. Symp. 97, 1-13 (1995).

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