Alkylation of alkyl, cycloalkyl and aralkyl halides

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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2606531R, 2606531T, 260658C, 260651R, C07C 1900, C07C 2310, C07C 2514

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active

040468194

ABSTRACT:
Alkyl, cycloalkyl or aralkyl halides may be alkylated by treatment with an olefin in the presence of a catalyst comprising a free-radical generating compound such as an organic peroxide and also in the presence of a promoter comprising hydrogen chloride, said alkylation reaction being effected at temperatures at least as high as the decomposition temperature of the free-radical generating compound, to prepare alkylated halide-containing compounds.

REFERENCES:
patent: 2058466 (1936-10-01), Kharasch
patent: 2404927 (1946-07-01), Schmerling et al.
patent: 2418832 (1947-04-01), Hanford et al.
patent: 2434289 (1948-01-01), Schmerling
patent: 2440800 (1948-05-01), Hanford
patent: 2440801 (1948-05-01), Hanford et al.
patent: 2533052 (1950-12-01), Schmerling
patent: 2985690 (1961-05-01), Miller
patent: 3592866 (1971-07-01), Magoon
patent: 3641171 (1972-02-01), Spooncer

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