Alkyl and aryl trifluoromethoxytetrafluorosulfuranes

Compositions – Liquid crystal compositions – Containing nonsteryl liquid crystalline compound of...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C549S374000, C560S109000, C568S027000

Reexamination Certificate

active

07025901

ABSTRACT:
Novel compositions containing SF4—O—CF3bonded to an organic group are disclosed. Aryl trifluoromethoxytetrafluorosulfuranes (or Ar—SF4—O—CF3), have been synthesized via the reaction of an aryl disulfide or thiol with fluoroxytrifluoromethane (F3COF). The compositions are useful synthons, which may be derivatized to yield highly electrically polar molecules, particularly novel liquid crystal compositions having high dielectric anisotropies. Cycloalkyl trifluoromethoxytetrafluorosulfuranes have similar utility.

REFERENCES:
patent: 5055223 (1991-10-01), Reiffenrath et al.
patent: 10008505 (2000-02-01), None
patent: 10018086 (2000-04-01), None
patent: 8810251 (1988-12-01), None
T. Inoi, “Fluorinated Liquid Crystals,” Organofluorine Chemistry, Ch. 12, 1994, pp. 263-286.
P. Kirsch, et al, “Nematic Liquid Crystals for Active . . . ,” Angew, Chem. Int. Ed., 2000, 39, pp. 4216-4235.
P. Kirsch, et al, “Liquid Crystals Based on . . . ,” Angew, Chem. Int. Ed. 1999, 38, pp. 1989-1992.
G. Pass, et al, “Some Reactions of Pentafluorosulfur . . . ,” Inorg. Chem. 2, 1963, pp. 1016-1019.
T. Kitazume, et al, “Some Chemistry of Fluorinated . . . ,” J. Am. Chem. Soc., 100, 1978, pp. 492-496.
D. B. Denny, et al, J. Am. Chem. Soc., 95, 1973, pp. 8191-8192.
X. Ou, et al, “Oxidative Addition and Isomerization . . . ,” Can. J. Chem., 75, 1997, pp. 1878-1884.
D.P. Curran, “Fluorous Reverse Phase . . . ,” Synlett, 9, 2001, pp. 1488-1496.
M. Brenner, et al, “Gas Phase Molecular . . . ,” Advanced Materials, 5, 1993, pp. 842-848.
LiqCryst: LC 1262 and LiqCryst: LC 4394; Liquid Crystal Group: Hamburg, Germany.
D.R. Lide, “Handbook of Chemistry and Physics”, Sec. 9, 1995, pp. 9-50.
W.A. Sheppard, “The Electrical Effect of the Sulfur . . . ,” J. Am. Chem. Soc., 84, 1962, pp. 3072-3076.
W.A. Sheppard, “Arylsulfur Pentafluorides,” J. Am. Chem. Soc., 84, 1962, pp. 3064-3072.
W.A. Sheppard, “The Effect of Fluorine Substitution . . . ,” J. Am. Chem. Soc., 85, 1963, pp. 1314-1318.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Alkyl and aryl trifluoromethoxytetrafluorosulfuranes does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Alkyl and aryl trifluoromethoxytetrafluorosulfuranes, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Alkyl and aryl trifluoromethoxytetrafluorosulfuranes will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3542805

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.