Algicidal and fungicidal 1-halo-2-substituted-thioethyl sulfones

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260607AR;, 260609R, 424337, 71 67, C07C14932, C07C14934, A01N 914, C07C14900

Patent

active

041961528

ABSTRACT:
1-Halo-2-alkylthioethyl and 1-halo-2-arylthioethyl sulfones, having algicidal and fungicidal activity, are prepared by the addition of arylsulfenyl or alkylsulfenyl halides to alkyl or aryl vinyl sulfones. The thioethyl sulfone products are treated with a base to produce 2-alkylthiovinyl or 2-arylthiovinyl sulfones, which also have algicidal and fungicidal activity. The vinyl sulfones are halogenated to produce 1,2-dihalothioethyl sulfones, which have superior fungicidal activity, especially for tomato and celery late blight.

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Chem. Abstracts 51: 5721f (1957).

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