Adhesion promotion for etch by-products

Semiconductor device manufacturing: process – Chemical etching – Vapor phase etching

Reexamination Certificate

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C438S710000, C134S001000, C134S001200

Reexamination Certificate

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10888461

ABSTRACT:
Methods and apparatus for cleaning a semiconductor substrate that significantly reduce the number of particles falling onto the substrate during cleaning by coating all interior surfaces within a processing chamber with an adhesion film that has an increased sticking coefficient for any subsequently arriving etched species to promote a continuous film growth and improve adhesion of such etched species. Due to its increased sticking coefficient, this adhesion film reduces surface mobility of any arriving by-products to enable the growth of the continuous film of etched species. The continuous film of etched species adheres firmly to the adhesion film such that the etched species are prevented from flaking off and falling onto the substrate being cleaned. The methods and apparatus may clean a plurality of semiconductor substrates, whereby a plurality of adhesion films are sequentially deposited over a plurality of continuous film growths of removed materials for cleaning the substrates.

REFERENCES:
patent: 5236868 (1993-08-01), Nulman
patent: 5988187 (1999-11-01), Trussell et al.
patent: 2003/0013314 (2003-01-01), Ying et al.
patent: 2003/0183244 (2003-10-01), Rossman

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