7-ethynyl-2,4,9-trithiaadamantane and related methods

Details 7-ethynyl-2,4,9-trithiaadamantane and related methods 7-ethynyl-2,4,9-trithiaadamantane and related methods

2008-10-31

2011-11-29

Dentz, Bernard (Department: 1622)

Compositions

Electrically conductive or emissive compositions

Metal compound containing

C257S040000

Reexamination Certificate

active

08066914

ABSTRACT:
7-ethynyl-2,4,9-trithiaadamantane and related methods are presented. Manufacturing 7-ethynyl-2,4,9-trithiaadamantane includes the steps of: (1) reducing alkyl 2,4,9-trithiaadamantane-7-carboxylate to produce 7-hydroxymethyl-2,4,9-trithiaadamantane; (2) oxidizing 7-hydroxymethyl-2,4,9-trithiaadamantane to produces 7-carbonyl-2,4,9-trithiaadamantane; and (3) reacting 7-carbonyl-2,4,9-trithiaadamantane with Ohira-Bestmann reagent to produces 7-ethynyl-2,4,9-trithiaadamantane. Molecular wires having 2,4,9-trithiaadamantane surface anchors are also disclosed.

REFERENCES:
patent: 3719710 (1973-03-01), Thomas et al.
patent: 4202892 (1980-05-01), Weiner et al.
patent: 5045551 (1991-09-01), Chandraratna et al.
patent: 5475341 (1995-12-01), Reed
patent: 5589692 (1996-12-01), Reed
patent: 6495323 (2002-12-01), Kayyem et al.
Bax, A., et al., “Practical Aspects of Two-Dimensional Transverse NOE Spectroscopy”, Journal of Magnetic Resonance, 63, 207-213 (1985).
Benesi, H.A., et al., “A Spectrophotometric Investigation of the Interaction of Iodine with Aromatic Hydrocarbons”, Journal of American Chemical Society, 1959, 71 (8), 2703-2707.
Kittredge, Kevin W., et al., “a-Helical Polypeptide Films Grown From Sulfide or Thiol Linkers on Gold Surfaces”, Helvetica Chimica Acta, 2002, 85, 788-798.

Affiliated with

Also associated with

Rating

7-ethynyl-2,4,9-trithiaadamantane and related methods does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with 7-ethynyl-2,4,9-trithiaadamantane and related methods, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and 7-ethynyl-2,4,9-trithiaadamantane and related methods will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-4306060