1,3-disilacyclobutanes and the method for producing thereof

Details 1,3-disilacyclobutanes and the method for producing thereof 1,3-disilacyclobutanes and the method for producing thereof

1992-06-11

1994-04-12

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

C07F 708

Patent

active

053027345

ABSTRACT:
The present invention relates to a process for preparing 1,3-disilacyclotutanes by pyrolyzing alkoxytrisilaalkaness at a temperature of from 400.degree. C. to 800.degree. C. at the atmospheric pressure or under the vacuum. This is a new synthetic route of 1,3-disilacyclobutanes which employs readily available starting materials without using alkaline metals or magnesium, affords very good yields, produces very clean product mixtures separable by distillation, and tolerates functionality on silicon.

REFERENCES:
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patent: 3178392 (1965-04-01), Kriner
patent: 4328350 (1982-05-01), Guselnikov et al.
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