Photopolymerizable composition

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Radiation sensitive composition or product or process of making

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430913, 430920, 430922, 522 34, 522 51, 522 53, 522 54, 522 57, 522 63, G03C 1729

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active

052387828

ABSTRACT:
A photopolymerizable composition comprises at least one addition polymerizable compound having at least one ethylenically unsaturated bond and at least one photopolymerization initiator represented by the following general formula (I): ##STR1## wherein R.sub.1 to R.sub.4 independently represent hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, hydroxyl group, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted amino group with the proviso that R.sub.1 to R.sub.4 may form a non-metallic ring together with the carbon atoms bonded thereto; R.sub.5 and R.sub.6 each represents hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a heteroaromatic group, an acyl group, cyano group, an alkoxycarbonyl group, carboxyl group or a substituted alkenyl group with the proviso that R.sub.5 and R.sub.6 may form a non-metallic ring together with the carbon atoms bonded thereto; X represents O, S, NH or a nitrogen atom having a substituent; and G.sub.1 and G.sub.2 each represents hydrogen atom, cyano group, a substituted or unsubstituted alkoxycarbonyl group, a substituted or unsubstituted aryloxycarbonyl group, a substituted or unsubstituted acyl group, a substituted or unsubstituted arylcarbonyl group, an alkylthio group, an arylthio group, an alkylsulfonyl group, an arylsulfonyl group or a fluorosulfonyl group with the proviso that G.sub.1 and G.sub.2 cannot simultaneously represent hydrogen atom and that G.sub.1 and G.sub.2 may form a non-metallic ring together with the carbon atoms bonded thereto. This composition provides light-sensitive layer of highly sensitive to light from a variety of light sources.

REFERENCES:
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patent: 4147552 (1979-04-01), Specht et al.
patent: 4272609 (1981-06-01), Klupfel
patent: 4289844 (1981-09-01), Specht et al.
patent: 4318791 (1982-03-01), Felder et al.
patent: 4366228 (1982-12-01), Specht et al.
patent: 4698286 (1987-10-01), Messer
patent: 4749643 (1988-06-01), Ohlschlager et al.
"Ketocoumarins as Photosensitizers and Photoinitiators" by J. L. R. Wiliams et al, Polymer Engineerig & Science, Dec. 1983, vol. 23, No. 18.
"Ketocoumarins" A New Class of Triplet Sensitizers, Specht et al, Tetrahedron, vol. 38, No. 9.

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