Photopolymerizable composition containing metallocenes

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Radiation sensitive composition or product or process of making

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430286, 430287, 430288, 430916, 430919, 430920, 430921, 430922, 522 31, 522 55, 522 63, 522 65, 522 66, 522 89, 522121, 522158, 522142, 260428, 544 64, 544225, 544164, 544165, G03C 168

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049101218

ABSTRACT:
Titanocenes containing .pi.-cyclopentadienyl ligands, in which one or two carbocyclic or heterocyclic aromatic rings are attached to the metal atom, said aromatic rings being substituted by fluorine in at least one of the two ortho-positions relative to the metal-carbon bonds, are suitable photoinitiators for the photopolymerization of ethylenically unsaturated substrates. They are distinguished by high sensitivity, stability to air and heat, and are very effective in the range from UV light to visible light.

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